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Tri(2-furyl)phosphine 三(2-呋喃基)磷化氢

规格: 97%

CAS: 5518-52-5

产品编号: H99563

MDL: MFCD00151857

品牌: INFI

Chemical Name	Tri(2-furyl)phosphine
CAS Number	5518-52-5
Synonym	Tri-2-furanylphosphine
MDL Number	MFCD00151857
EC Number	000-000-0
Beilstein Registry Number	1577564
PubChem Substance ID	521585
Chemical Name Translation	三(2-呋喃基)膦
Reaxys-RN	1577564
LabNetwork Molecule ID	LN00188600
InChI	InChI=1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H
Canonical SMILES	P(C1=CC=CO1)(C2=CC=CO2)C3=CC=CO3

磷化氢配体，用于过渡金属介入的有机合成；也用于Wittig 反应。

{ALF} In a study of Pd-catalyzed coupling reactions in supercritical CO 2, this ligand was among the best tried in both the Stille and Heck reactions, giving much superior results to e.g. triphenyl- or tri(o-tolyl)phosphine: Chem. Commun., 1397 (1998). See also Tris[3,5-bis(trifluoromethyl)phenyl]phosphine, L06941.

{ALF} Best ligand for Pd-catalyzed coupling of 5-iodouracil and unsaturated tributylstannanes: Synlett, 157 (1991).

{uni_hamburg} Short: III/35C4

{ALD} Beilstein:18(5)12,505

{ALF} Large rate enhancements (10 2 -10 3 ) over triphenylphosphine are observed in Pd-catalyzed coupling of olefinic stannanes and electrophiles: J. Am. Chem. Soc ., 113, 9585 (1991).

{TRC} Andersen N.G. et al.: Chem. Rev., 101, 997 (2001); Appel M. et al.: Eur. J. Org. Chem., 1143, (2002);

5518-52-5 H99563 Tri(2-furyl)phosphine 三(2-呋喃基)磷化氢

化学属性

Mol. Formula	C12H9O3P
Mol. Weight	232.18
Melting Point	59 - 64 °C - lit
TSCA	No
Boiling Point	136 °C 在 4 mmHg - lit.
Density	1.422
Flash Point	136°C/4mm
Appearance	white pwdr.
Stability	air sensitive

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Tri(2-furyl)phosphine 三(2-呋喃基)磷化氢

规格: 97%

化学属性

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