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Tri(2-furyl)phosphine 三(2-呋喃基)磷化氢

规格: 97%
CAS: 5518-52-5
产品编号: H99563
MDL: MFCD00151857
品牌: INFI
Chemical NameTri(2-furyl)phosphine
CAS Number5518-52-5
Synonym Tri-2-furanylphosphine {LY} Tri-2-furanylphosphine tri-2-furylphosphine {} {LY} Tri-2-furanylphosphine {} {} {LY} Tri-2-furanylphosphine {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00151857
EC Number000-000-0
Beilstein Registry Number1577564
PubChem Substance ID521585
Chemical Name Translation三(2-呋喃基)膦
Reaxys-RN1577564
LabNetwork Molecule IDLN00188600
InChIInChI=1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H
Canonical SMILESP(C1=CC=CO1)(C2=CC=CO2)C3=CC=CO3
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
    Risk Statements
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      Signal word Warning
      WGK Germany3
      Precautionary statements
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P264+P265
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P302+P350
      • P302+P352
      • P304+P340
      • P305+P351+P338
      • P305+P351+P338+P337+P313
      • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
      • P319
      • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
      • P332+P313
      • P332+P317
      • P337+P313
      • P337+P317
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      • P362+P364
      • P403+P233
      • P405 Store locked up. 上锁保管。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H315 Causes skin irritation 会刺激皮肤
        • H319 Causes serious eye irritation 严重刺激眼睛
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
          Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
          Hazard Codes Xi
          Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Store at room temperature {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, prote
        • 磷化氢配体，用于过渡金属介入的有机合成； 也用于Wittig 反应。
        • {ALF} In a study of Pd-catalyzed coupling reactions in supercritical CO 2, this ligand was among the best tried in both the Stille and Heck reactions, giving much superior results to e.g. triphenyl- or tri(o-tolyl)phosphine: Chem. Commun., 1397 (1998). See also Tris[3,5-bis(trifluoromethyl)­phenyl­]phosphine, L06941.
        • {ALF} Best ligand for Pd-catalyzed coupling of 5-iodouracil and unsaturated tributylstannanes: Synlett, 157 (1991).
        • {uni_hamburg} Short: III/35C4
        • {ALD} Beilstein:18(5)12,505
        • {ALF} Large rate enhancements (10 2 -10 3 ) over triphenylphosphine are observed in Pd-catalyzed coupling of olefinic stannanes and electrophiles: J. Am. Chem. Soc ., 113, 9585 (1991).
        • {TRC} Andersen N.G. et al.: Chem. Rev., 101, 997 (2001); Appel M. et al.: Eur. J. Org. Chem., 1143, (2002);
          • 5518-52-5 H99563 Tri(2-furyl)phosphine 三(2-呋喃基)磷化氢

          化学属性

          Mol. FormulaC12H9O3P
          Mol. Weight232.18
          Melting Point59 - 64 °C - lit
          TSCANo
          Boiling Point136 °C 在 4 mmHg - lit.
          Density1.422
          Flash Point136°C/4mm
          Appearance white pwdr.
          Stabilityair sensitive

          *以上化合物性质及应用等信息仅供参考

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