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Tri(o-tolyl)phosphine 三(邻甲苯基)膦

规格: 98%
CAS: 6163-58-2
产品编号: H97472
MDL: MFCD00008514
品牌: INFI
Chemical NameTri(o-tolyl)phosphine
CAS Number6163-58-2
Alfabeta NameTRITOLYLPHOSPHINE M()-
MDL NumberMFCD00008514
Synonym Tri(2-methylphenyl)phosphine
EC Number228-193-9
Beilstein Registry Number661212
PubChem Substance ID80271
Reaxys-RN661212
Chemical Name Translation三(邻甲苯基)膦
InChIKeyCOIOYMYWGDAQPM-UHFFFAOYSA-N
LabNetwork Molecule IDLN00173237
InChIInChI=1S/C21H21P/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3/h4-15H,1-3H3
Canonical SMILESCC1=C(C=CC=C1)P(C(C=CC=C2)=C2C)C(C=CC=C3)=C3C
  • 配体,用于钌催化的醇的氨基化反应。
  • {uni_hamburg} Short: III/10b
  • {uni_hamburg} Short: EINECS
  • {ALF} Preferred phosphine ligand for use in combination with Pd salts in the Heck-type coupling reactions of vinylic halides. For examples, see Palladium(II)­ acetate, 10516. For a review of the Heck reaction, see: Org. React., 27, 345 (1982).
  • {ALF} The Pd-catalyzed amination of bromoarenes with 1-Boc-piperazine, L13363, in the presence of this ligand, provides a route to arylpiperazines of potential pharmacological interest: Tetrahedron Lett., 39, 2219 (1998).
  • {ALD} Beilstein: 16,III,835
  • 6163-58-2 H97472 Tri(o-tolyl)phosphine
三(邻甲苯基)膦

    化学属性

    Mol. FormulaC21H21P
    Mol. Weight304.37
    Density1.589
    Melting Point123-125°C
    TSCAYes
    Boiling Point412.4±44.0 °C at 760 mmHg
    Appearance white xtl.
    Stabilityair sensitive

    *以上化合物性质及应用等信息仅供参考