DoMole-安徽敦茂科技

Triethylborane 三乙基硼

规格: 1.0 M solution in THF, SpcSeal

CAS: 97-94-9

产品编号: H93372

MDL: MFCD00009022

品牌: INFI

Chemical Name	Triethylborane
MDL Number	MFCD00009022
CAS Number	97-94-9
Synonym	(C2H5)3B TRIETHYLBORANE TRIETHYLBORANE SOLUTION, ~15% IN HEXANE TRIETHYLBORANE, 95+% Triethylborane Triethylborane (1.0 M in THF) Triethylborane (ca. 11% in Tetrahydrofuran, ca. 1mol/L) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	87577677
Beilstein Registry Number	1731462
EC Number	202-620-9
Reaxys-RN	1731462
Merck Number	9668
Chemical Name Translation	三乙基硼
Wiswesser Line Notation	2B2&2
LabNetwork Molecule ID	LN00164556
InChI	InChI=1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3
Canonical SMILES	CCB(CC)CC

GHS Symbol

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 700 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New
   York, John Wiley & Sons, Inc., 1964  Volume(issue)/page/year: -,693,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 22700 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New
   York, John Wiley & Sons, Inc., 1964  Volume(issue)/page/year: -,693,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 235 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New
   York, John Wiley & Sons, Inc., 1964  Volume(issue)/page/year: -,693,1964

WGK Germany	1
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。 P222 Do not allow contact with air. 不要与空气接触。 P231+P232 P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。 P241+P242+P243 P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。 P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P301+P330+P331+P310 P303+P361+P353 P303+P361+P353+P310+P363 P304+P340 P304+P340+P310 P305+P351+P338 P305+P351+P338+P310 P308+P311 P370+P378 P403+P233 P405 Store locked up. 上锁保管。 P422 Store contents under… 存储目录在…之下。 P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤 H335 May cause respiratory irritation 可能导致呼吸道刺激 H351 Suspected of causing cancer 怀疑致癌 H261 In contact with water releases flammable gas 与水接触时释放可燃气体。 H225 Highly flammable liquid and vapour 高度易燃液体和蒸气 H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火 H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命 H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕 H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。 H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害 H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官 H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment	Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word	Danger
RTECS	ED2100000
Safety Statements
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S33 Take precautionary measures against static discharges 对静电采取预防措施； S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水” S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）； S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签； S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Packing Group	II
UN Number	2924 3399
Risk Statements
R11 Highly flammable 非常易燃 R17 Spontaneously flammable in air 在空气中能够自燃 R19 May form explosive peroxides 可能生成易爆的过氧化物质 R22 Harmful if swallowed 吞咽有害 R34 Causes burns 会导致灼伤 R37 Irritating to respiratory system 刺激呼吸道 R48/20 R51/53 R62 Possible risk of impaired fertility 有削弱生殖能力的危险 R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官 R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Storage condition	0-6°C 93.0 Air Sensitive N/A N/A℃ No Data Available 充氩保存充氩密封2-8°C保存
Hazard Codes	4.3 F,C F,Xn,N F;C;N
Hazard Class	3/8
Warnings	危化品目录(2015)
Restrict	危险品

Usually used as catalyst for Allylation of aldehydes,Decarboxylative C-C bond cleavage reactions,Regioselective hydroxyalkylation of unsaturated oxime ethers.And also used as reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes,synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential.

{uni_hamburg} Short: III/38A

{ALD} Merck: 14,9668

{ALF} Reacts with metal enolates to give the enoxytriethylborates, useful in selective alkylation and aldol reactions: Tetrahedron Lett., 2975 (1976); 32, 5521 (1991).

{uni_hamburg} Short: III/20a

{ALF} Radical initiator for hydrostannylation of alkynes: Tetrahedron, 45, 923 (1989).

{uni_hamburg} Short: III/35A

{ALD} Merck: 14,9668

Beilstein:4(4)4359

化学属性

Mol. Formula	C6H15B
Mol. Weight	97.99
Density	0.8572
Flash Point	32.8°F
TSCA	Yes
Refractive index	n20/D 1.397(lit.)
Melting Point	-93
Boiling Point	95°C
Solubility	分解
Stability	对空气敏感.
Appearance	colorless liq.

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

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Triethylborane 三乙基硼

规格: 1.0 M solution in THF, SpcSeal

化学属性

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