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Triethylborane 三乙基硼

规格: 1.0 M solution in THF, SpcSeal
CAS: 97-94-9
产品编号: H93372
MDL: MFCD00009022
品牌: INFI
Chemical NameTriethylborane
MDL NumberMFCD00009022
CAS Number97-94-9
Synonym Triethylborane (1.0 M in THF) Triethylborane (ca. 11% in Tetrahydrofuran, ca. 1mol/L)
PubChem Substance ID87577677
Beilstein Registry Number1731462
EC Number202-620-9
Reaxys-RN1731462
Merck Number9668
Chemical Name Translation三乙基硼
Wiswesser Line Notation2B2&2
LabNetwork Molecule IDLN00164556
InChIInChI=1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3
Canonical SMILESCCB(CC)CC
IUPAC Nametriethylborane
  • Usually used as catalyst for Allylation of aldehydes,Decarboxylative C-C bond cleavage reactions,Regioselective hydroxyalkylation of unsaturated oxime ethers.And also used as reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes,synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential.
  • {PUB} Crystallography Open Database (COD)|PubChem|The Cambridge Structural Database --- Deoxygenative [1,2]-Hydride Shift Rearrangements in Nucleoside and Sugar Chemistry: Analogy with the [1,2]-Electron Shift in the Deoxygenation of Ribonucleotides by Ribonucleotide Reductases1 --- https://pubmed.ncbi.nlm.nih.gov/17918996
  • {ALD} Merck: 14,9668
  • {ALD} Merck: 14,9668 Beilstein:4(4)4359
  • {PUB} Nature Chemistry|PubChem|Springer Nature --- Towards high-performance sustainable polymers via isomerization-driven irreversible ring-opening polymerization of five-membered thionolactones --- https://pubmed.ncbi.nlm.nih.gov/34824460
  • {PUB} PubChem --- A convenient allylsilane-N-acyliminium route toward indolizidine and quinolizidine alkaloids --- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2148044
  • {PUB} PubChem --- Catalytic Intermolecular Enal−Alkyne [3 + 2] Reductive Cycloadditions --- https://pubmed.ncbi.nlm.nih.gov/17061877
  • {PUB} PubChem --- Complexes of Borane and N-Heterocyclic Carbenes: A New Class of Radical Hydrogen Atom Donor --- https://pubmed.ncbi.nlm.nih.gov/18611014
  • {PUB} PubChem --- Direct observation of the unstable intermediates in radical addition reaction by using an interfacing microchip combined with an NMR --- https://pubmed.ncbi.nlm.nih.gov/17924352
  • {PUB} PubChem --- Erratum: Structure elucidation of the intermediate in triethylborane‐mediated radical addition of oxime ethers with 2D‐ and 3D‐DOSY NMR --- https://pubmed.ncbi.nlm.nih.gov/16729260
  • {PUB} PubChem --- Et3B-Induced Radical Addition of N,N-Dichlorosulfonamide to Alkenes and Pyrrolidine Formation via Radical Annulation --- https://pubmed.ncbi.nlm.nih.gov/12688798
  • {PUB} PubChem --- Hydroxyalkylation of α-C−H Bonds of Tetrahydrofuran with Aldehydes in the Presence of Triethylborane and tert-Butyl Hydroperoxide --- https://pubmed.ncbi.nlm.nih.gov/12530897
  • {PUB} PubChem --- Macrocyclization by Nickel‐Catalyzed, Ester‐Promoted, Epoxide–Alkyne Reductive Coupling: Total Synthesis of (−)‐Gloeospor
  • 97-94-9 H93372 Triethylborane
三乙基硼

    化学属性

    Mol. FormulaC6H15B
    Mol. Weight97.99
    Density0.86
    Flash Point32.8°F
    TSCAYes
    Refractive indexn20/D 1.397(lit.)
    Melting Point-93
    Boiling Point95°C
    Solubility分解
    Stability对空气敏感.
    Appearance colorless liq.

    *以上化合物性质及应用等信息仅供参考