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Triethylborane 三乙基硼

规格: 1.0 M solution in THF, SpcSeal
CAS: 97-94-9
产品编号: H93372
MDL: MFCD00009022
品牌: INFI
Chemical NameTriethylborane
MDL NumberMFCD00009022
CAS Number97-94-9
Synonym Triethylborane (1.0 M in THF) Triethylborane (ca. 11% in Tetrahydrofuran, ca. 1mol/L)
PubChem Substance ID87577677
Beilstein Registry Number1731462
EC Number202-620-9
Reaxys-RN1731462
Merck Number9668
Chemical Name Translation三乙基硼
Wiswesser Line Notation2B2&2
LabNetwork Molecule IDLN00164556
InChIInChI=1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3
Canonical SMILESCCB(CC)CC
  • Usually used as catalyst for Allylation of aldehydes,Decarboxylative C-C bond cleavage reactions,Regioselective hydroxyalkylation of unsaturated oxime ethers.And also used as reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes,synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential.
  • {uni_hamburg} Short: III/38A
  • {ALD} Merck: 14,9668
  • {ALF} Reacts with metal enolates to give the enoxytriethylborates, useful in selective alkylation and aldol reactions: Tetrahedron Lett., 2975 (1976); 32, 5521 (1991).
  • {uni_hamburg} Short: III/20a
  • {ALF} Radical initiator for hydrostannylation of alkynes: Tetrahedron, 45, 923 (1989).
  • {uni_hamburg} Short: III/35A
  • {ALD} Merck: 14,9668
  • Beilstein:4(4)4359
  • 97-94-9 H93372 Triethylborane
三乙基硼

    化学属性

    Mol. FormulaC6H15B
    Mol. Weight97.99
    Density0.86
    Flash Point32.8°F
    TSCAYes
    Refractive indexn20/D 1.397(lit.)
    Melting Point-93
    Boiling Point95°C
    Solubility分解
    Stability对空气敏感.
    Appearance colorless liq.

    *以上化合物性质及应用等信息仅供参考