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(Carbethoxymethyl)triphenylphosphonium bromide 乙氧甲酰基甲基三苯基溴化鏻

规格: 98%
CAS: 1530-45-6
产品编号: H87798
MDL: MFCD00011835
品牌: INFI
Chemical Name(Carbethoxymethyl)triphenylphosphonium bromide
Synonym (2-Ethoxy-2-oxoethyl)triphenylphosphonium bromide
Beilstein Registry Number3581273
PubChem Substance ID73731
CAS Number1530-45-6
EC Number216-230-1
MDL NumberMFCD00011835
Reaxys-RN3581273
Chemical Name Translation乙氧甲酰基甲基三苯基溴化鏻
InChIKeyVJVZPTPOYCJFNI-UHFFFAOYSA-M
Wiswesser Line Notation2OV1PR&R&R &E &5/13
LabNetwork Molecule IDLN00190334
InChIInChI=1S/C22H22O2P.BrH/c1-2-24-22(23)18-25(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-17H,2,18H2,1H3;1H/q+1;/p-1
Canonical SMILESO=C(OCC)C[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Br-]
IUPAC Name(2-ethoxy-2-oxoethyl)-triphenylphosphanium bromide
  • {ALD} Beilstein: 16,IV,980
  • {PUB} ChemIDplus --- U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals., NX#12281 ---
  • {ALFA} For reaction with trifluoroacetic anhydride and triethylamine, followed by pyrolysis as a route to perfluoroalkyl acetylenes, see: Org. Synth. Coll., 9, 436 (1998):
  • {PUB} Thieme Chemistry --- Alkylation of Phosphines with α-(Halomethyl)carbonyl Species --- https://science-of-synthesis.thieme.com/app/text/?id=SD-042-00577
  • {PUB} Thieme Chemistry --- Condensation of Esters with Organophosphorus Reagents (Wittig-like Reaction) --- https://science-of-synthesis.thieme.com/app/text/?id=SD-032-00674
  • {PUB} Thieme Chemistry --- Cyclization of γ-Oxo Acids --- https://science-of-synthesis.thieme.com/app/text/?id=SD-109-00807
  • {PUB} Thieme Chemistry --- Modification of Ketones, Aldehydes, and Derivatives --- https://science-of-synthesis.thieme.com/app/text/?id=SD-016-00449
  • {PUB} Thieme Chemistry --- Reaction of Stabilized Ylides with Other Electrophiles --- https://science-of-synthesis.thieme.com/app/text/?id=SD-042-00579
  • {PUB} Thieme Chemistry --- Reaction of[(Alkoxycarbonyl)methylene]triphenylphosphoranes with Acyl Chlorides, Anhydrides, or Carboxylic Acids --- https://science-of-synthesis.thieme.com/app/text/?id=SD-020-01193
  • {PUB} Thieme Chemistry --- Reaction of[(Ethoxycarbonyl)iodomethyl]triphenylphosphonium Iodide with Aldehydes --- https://science-of-synthesis.thieme.com/app/text/?id=SD-020-01194
  • 1530-45-6 H87798 (Carbethoxymethyl)triphenylphosphonium bromide
乙氧甲酰基甲基三苯基溴化鏻

    化学属性

    Mol. FormulaC22H22BrO2P
    Mol. Weight429.29
    Melting Point145-150°C
    TSCANo
    Density1.505
    Stability易吸潮

    *以上化合物性质及应用等信息仅供参考