• QQ: 1811068585
  • Hotline: +86 13275595566

Silver trifluoromethanesulfonate 三氟甲烷磺酸银

规格: 98%
CAS: 2923-28-6
产品编号: H87360
MDL: MFCD00013226
品牌: INFI
Chemical NameSilver trifluoromethanesulfonate
CAS Number2923-28-6
Alfabeta NameSILVERTRIFLUOROMETHANESULFONATE
MDL NumberMFCD00013226
EC Number220-882-2
Beilstein Registry Number3598402
Synonym Silver trifluoromethanesulfonate
PubChem Substance ID76223
Reaxys-RN3598402
Chemical Name Translation三氟甲烷磺酸银
InChIKeyQRUBYZBWAOOHSV-UHFFFAOYSA-M
LabNetwork Molecule IDLN00115656
InChIInChI=1S/CHF3O3S.Ag/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
Canonical SMILESO=S(C(F)(F)F)([O-])=O.[Ag+]
  • {ALF} Silver salt soluble in ether, fairly soluble in benzene and toluene, less soluble in acetonitrile and insoluble in chloroform and dichloromethane; useful, e.g. in promotion of the leaving ability of halogens. For use in the conversion of alkyl halides to triflates, see: J. Chem. Soc., 173 (1956); J. Am. Chem. Soc., 90, 1598 (1968); Tetrahedron Lett., 3159 (1970); J. Chem. Soc., Perkin 1, 2887 (1980). Review: Synthesis, 85 (1982).
  • {ALF} For use as a catalyst for the oxy-Cope rearrangement of allyl alkynyl carbinols, where other silver salts are ineffective, see: Tetrahedron Lett., 25, 2873 (1984):
  • {ALF} Acyl halides are converted to acyl triflates, powerful acylating reagents, which can bring about Friedel-Crafts-type acylation without added Lewis acid catalyst: Chem. Ber., 116, 1195 (1983).
  • {ALF} Reaction with chlorosilanes gives silyl triflates, powerful silylating reagents, and, likewise trialkyltin halides are converted to the corresponding triflates: Chem. Ber., 103, 868 (1970).
  • {ALD} Beilstein:3(4)34
  • {SNA}
  • 2923-28-6 H87360 Silver trifluoromethanesulfonate
三氟甲烷磺酸银

    化学属性

    Mol. FormulaCAgF3O3S
    Mol. Weight256.94
    Melting Point283 - 289 °C(lit.)
    Density1.876
    TSCAT
    Stability易吸潮
    Appearance off-white pwdr.

    *以上化合物性质及应用等信息仅供参考