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2,4,6-Triphenylpyrylium tetrafluoroborate 2,4,6-三苯基吡喃四氟硼酸盐

规格: 99%
CAS: 448-61-3
产品编号: H84484
MDL: MFCD00012001
品牌: INFI
Chemical Name2,4,6-Triphenylpyrylium tetrafluoroborate
MDL NumberMFCD00012001
CAS Number448-61-3
Beilstein Registry Number3586533
EC Number207-186-4
PubChem Substance ID9930615
Synonym 2,4,6-Triphenylpyrylium tetrafluoroborate
Chemical Name Translation2,4,6-三苯基吡喃四氟化硼盐
InChIKeyVQYPWMWEJGDSTF-UHFFFAOYSA-N
Wiswesser Line NotationT6OJ BR& DR& FR &.B-F4 &3/19
LabNetwork Molecule IDLN00201404
InChIInChI=1S/C23H17O.BF4/c1-4-10-18(11-5-1)21-16-22(19-12-6-2-7-13-19)24-23(17-21)20-14-8-3-9-15-20;2-1(3,4)5/h1-17H;/q+1;-1
Canonical SMILESFB(F)F.C1(C2=CC=CC=C2)=CC(C3=CC=CC=C3)=CC(C4=CC=CC=C4)=[O+]1.[F-]
IUPAC Name2,4,6-triphenylpyrylium tetrafluoroborate
  • {ALF} Amines react with pyrylium salts to give N-alkylpyridinium salts. Since the pyridine can be displaced by a variety of nucleophiles, the result is that the amine has been converted to a useful alkylating species: J. Chem. Soc., Perkin 1, 418 (1979). Reviews: Tetrahedron, 36, 679 (1980); Angew. Chem. Int. Ed., 23, 420 (1984); Russ. Chem. Rev., 51, 469 (1982):
  • {ALF} For a review on use as an electron-transfer photosensitizer, see: Chem. Rev., 94, 1063 (1994).
  • {PUB} PubChem --- The Role of Aromatic Radical Cations and Benzylic Cations in the 2,4,6-Triphenylpyrylium Tetrafluoroborate Photosensitized Oxidation of Ring-Methoxylated Benzyl Alcohols in CH2Cl2 Solution --- https://pubmed.ncbi.nlm.nih.gov/15575769
  • {PUB} PubChem|Springer Nature --- Capillary and microchip electrophoretic analysis of polycyclic aromatic hydrocarbons --- https://pubmed.ncbi.nlm.nih.gov/25542576
  • {PUB} PubChem|Springer Nature --- Direct Amination of Aromatic C–H Bonds with Free Amines --- https://pubmed.ncbi.nlm.nih.gov/32236795
  • {PUB} PubChem|Springer Nature --- Involvement of triplet excited states in the electron transfer photodegradation of cinnamic acids using pyrylium and thiapyrylium salts as photocatalysts --- https://pubmed.ncbi.nlm.nih.gov/17668114
  • {PUB} PubChem|Springer Nature --- Photosensitiser-controlled regioselectivity in the electron-transfer cycloreversion of 2,3-diphenyloxetanes --- https://pubmed.ncbi.nlm.nih.gov/14521220
  • {PUB} PubChem|Springer Nature --- Reactions of Organic Ions at Ambient Surfaces in a Solvent-Free Environment --- https://pubmed.ncbi.nlm.nih.gov/22290484
  • {PUB} PubChem|Springer Nature --- Sensitized photooxygenation of the fungicide furalaxyl --- https://pubmed.ncbi.nlm.nih.gov/15341311
  • {PUB} Springer Nature --- Catalytic Reduction of Pyridinium, Pyrylium, and Thiopyrylium Salts. (Review) --- https://doi.org/10.1023/a:1012491504815
  • {PUB} Springer Nature --- Direct detection of photo-induced reactions by IR: from Brook rearrangement to photo-cata
  • 448-61-3 H84484 2,4,6-Triphenylpyrylium tetrafluoroborate
2,4,6-三苯基吡喃四氟硼酸盐

    化学属性

    Mol. FormulaC23H17BF4O
    Mol. Weight396.19
    Melting Point250-251 °C
    TSCANo
    Density1.0

    *以上化合物性质及应用等信息仅供参考