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Cyclopentadienylmanganese(I) tricarbonyl 三羰基环戊二烯锰(I)

规格: 98%

CAS: 12079-65-1

产品编号: H77287

MDL: MFCD00001440

品牌: INFI

Chemical Name	Cyclopentadienylmanganese(I) Tricarbonyl
MDL Number	MFCD00001440
PubChem Substance ID	24857312
CAS Number	12079-65-1
EC Number	235-142-4
Synonym	Cyclopentadienyltricarbonylmanganese; Cymantrene; Manganese cyclopentadienyltricarbonyl Cyclopentadienylmangantricarbonyl Manganese cyclopentadienyltricarbonyl Manganese, tricarbonyl(η(5)-2,4-cyclopentadien-1-yl)- Manganese cyclopentadienyl tricarbonyl h5-Cyclopentadienylmanganese tricarbonyl Cyclopentadienylmanganese tricarbonyl Tricarbonylcyclopentadienylmanganese η⁵-Cyclopentadienylmanganese tricarbonyl Tricarbonyl(η5-2,4-cyclopentadien-1-yl)mangan Cymantrene Manganese, tricarbonyl(η⁵-2,4-cyclopentadien-1-yl)- Cyklopentadientrikarbonylmanganium Manganese, tricarbonyl(h5-2,4-cyclopentadien-1-yl)- Manganese, tricarbonyl(η5-2,4-cyclopentadien-1-yl)- p-Cyclopentadienylmanganese tricarbonyl Manganese, tricarbonyl-p-cyclopentadienyl- tricarbonyl(η-cyclopentadienyl)manganese 三羰基环戊二烯锰(I) Cyclopentadienyl-p-tricarbonylmanganese Manganese, tricarbonyl-pi-cyclopentadienyl- Tricarbonyl(η⁵-cyclopentadienyl)manganese(I) Tricarbonyl(h5-cyclopentadienyl)manganese Tricarbonyl-p-cyclopentadienylmanganese Cyclopentadienyl-manganese-tricarbonyl tricarbonyl(η cyclopentadienyl)manganese Tricarbonyl(η⁵-2,4-cyclopentadien-1-yl)manganese Cyclopentadienyltricarbonylmanganese
Chemical Name Translation	三羰基环戊二烯合锰
Wiswesser Line Notation	L5J A-MN-VHVHVH

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 710 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#11285

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 14 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - chronic pulmonary edema
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 34,341,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 22 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 34,341,1985

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 120 mg/m3/2H
TOXIC EFFECTS :
   Vascular - BP lowering not characterized in autonomic section
   Blood - hemorrhage
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   HYSAAV Hygiene and Sanitation (USSR).  English translation of GISAAA.
   (Springfield, VA)  1964-71. Discontinued.  Volume(issue)/page/year:
   30(4-6),40,1965

RTECS	OO9720000
WGK Germany	3
Precautionary statements
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P301+P310
Hazard statements
H300 Fatal if swallowed 吞食致命
Hazard Codes	T+
Personal Protective Equipment	Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word	Danger
Safety Statements
S20 When using do not eat or drink 使用时，不得进食，饮水； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）； S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗； S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S9 Keep container in a well-ventilated place 保持容器在通风良好的场所； S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
UN Number	UN3466
Risk Statements
R28 Very toxic if swallowed 吞咽极毒 R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
Storage condition	Air Sensitive
Packing Group	II

{SA}

Beil. 16 ,IV,1777

{SA}

Corp MSDS 1 (1), 983:A / FT-IR 2 (3), 4582:D / FT-NMR 1 (3), 779:B / RegBook 1 (2), 3135:C / Sax 6 , 842 / Structure Index 1 , 495:D:7

{uni_hamburg} Short: II/24A

Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, l-type, Centrifugal Distortion and Related Constants of Diamagnetic Diatomic, Linear, and Symmetric Top Molecules

Author: Demaison, J.; Hübner, H.; Wlodarczak, G.

Editor: Hüttner, W.

Source: Landolt-Börnstein, New Series

Volume: II/24A

Year: 1998

Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules

ISBN: 3-540-63267-0

ISBN: 978-3-540-63267-2

Internet Resource: DOI:10.1007/b60165

RefComment: VIII, 286 pages. Hardcover

Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24A contains the general introduction and tables of rotational and centrifugal distortion constants of diamagnetic diatomic, linear and symmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.

{uni_hamburg} Short: II/24C

Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Interaction Constants of Diamagnetic

12079-65-1 H77287 Cyclopentadienylmanganese(I) tricarbonyl
三羰基环戊二烯锰(I)

化学属性

Mol. Formula	C5H5Mn(CO)3
Mol. Weight	204
Melting Point	77°C
TSCA	Yes
Appearance	yellow xtl.
Stability	air sensitive
Density	1.0

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

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Cyclopentadienylmanganese(I) tricarbonyl 三羰基环戊二烯锰(I)

规格: 98%

化学属性

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