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(S)-(-)-XylBINAP (S)-(-)-2,2'-双[二(3,5-二甲基苯基膦)]-1,1'-联萘

规格: 98%

CAS: 135139-00-3

产品编号: H75993

MDL: MFCD01630821

品牌: INFI

Chemical Name	(S)-2,2’-Bis(bis(3,5-Dimethylphenyl)Phosphino)-1,1’-Binaphthalene
Synonym	(R)-(+)-1,1′-联萘-2,2′-二基)二[双(3,5-二甲基苯基)膦] (R)-(+)-2,2′-双[二(3,5-二甲苯基)膦]-1,1′-联萘 (R)-Xylyl-BINAP (S)-(-)-2,2′-双[二(3,5-二甲苯基)膦]-1,1′-联萘 (S)-DM-BINAP (S)-联萘(3,5-二甲苯基)膦 (S)-联萘(3,5-二甲苯基)膦 (S)-(-)-2,2′-双[二(3,5-二甲苯基)膦]-1,1′-联萘
MDL Number	MFCD01630821
CAS Number	135139-00-3
Chemical Name Translation	(S)-2,2’-双[二(3,5-二甲基苯基膦)]-1,1’-联萘
Reaxys-RN	4344206
PubChem Substance ID	329761554

WGK Germany	3
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S37 Wear suitable gloves 戴适当手套；
Risk Statements
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Personal Protective Equipment	Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

{SA} Evans, P. A.; et al., Regiodivergent Ligand-Controlled Rhodium-Catalyzed [(2+2)+2] Carbocyclization Reactions with Alkyl Substituted Methyl Propiolates Angew. Chem. Int. Ed. Engl. 49 , 5746-5749, (2010)

{SA} Goto, M.; et al., Process Research on the Asymmetric Hydrogenation of a Benzophenone for Developing the Manufacturing Process of the Squalene Synthase Inhibitor TAK-475 Org. Process Res. Dev. 15 , 1178-1184, (2011)

{SA} Kiyooka, S.; et al., Platinum(II) complex-catalyzed enantioselective aldol reaction with ketene silyl acetals in DMF at room temperature Tetrahedron 66 , 1806-1816, (2010)

{SA} Menard, F.; et al., Ligand-Controlled Selectivity in the Desymmetrization of meso Cyclopenten-1,4-diols via Rhodium(I)-Catalyzed Addition of Arylboronic Acids J. Org. Chem. 75 , 4056-4068, (2010)

{SA} Ogaki, S.; et al., Enantioselective Synthesis of Axially Chiral Hydroxy Carboxylic Acid Derivatives by Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition J. Org. Chem. 76 , 1926-1929, (2011)

{SA} Oppenheimer, J.; et al., A rhodium(I)-xylyl-BINAP catalyzed asymmetric ynamide-[2+2+2] cycloaddition in the synthesis of optically enriched N,O-biaryls Tetrahedron 65 , 5001-5012, (2009)

135139-00-3 H75993 (S)-(-)-XylBINAP
(S)-(-)-2,2'-双[二(3,5-二甲基苯基膦)]-1,1'-联萘

化学属性

Mol. Formula	C52H48P2
Mol. Weight	734.90
Melting Point	203-206°C
TSCA	No
Appearance	white to pale yellow xtl.
Density	1.0

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

(S)-(-)-XylBINAP (S)-(-)-2,2'-双[二(3,5-二甲基苯基膦)]-1,1'-联萘

规格: 98%

化学属性

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