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2-(Trimethylsilyl)ethanol 2-三甲基硅基乙醇

规格: 95%

CAS: 2916-68-9

产品编号: H73162

MDL: MFCD00002825

品牌: INFI

Chemical Name	2-(Trimethylsilyl)ethanol
CAS Number	2916-68-9
Alfabeta Name	TRIMETHYLSILYLETHANOL 2-
MDL Number	MFCD00002825
Synonym	(2-Hydroxyethyl)trimethylsilane {LY} (2-Hydroxyethyl)trimethylsilane {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} { {} {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number	220-844-5
Beilstein Registry Number	1732034
PubChem Substance ID	87577204
Reaxys-RN	1732034
Chemical Name Translation	2-三甲基硅基乙醇
InChIKey	ZNGINKJHQQQORD-UHFFFAOYSA-N
Wiswesser Line Notation	Q2-SI-1&1&1
LabNetwork Molecule ID	LN00009690
InChI	InChI=1S/C5H14OSi/c1-7(2,3)5-4-6/h6H,4-5H2,1-3H3
Canonical SMILES	C[Si](CCO)(C)C

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1122 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DANKAS Doklady Akademii Nauk SSSR.  Proceedings of the Academy of Sciences
   of the USSR.  For English translation, see DBIOAM and DKBSAS.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-    1933-
   Volume(issue)/page/year: 229,1011,1976

Warnings	FLAMMABLE
Signal word	Warning
WGK Germany	3
Safety Statements
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟； S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
R10 Flammable 易燃 R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。 P233 Keep container tightly closed. ?保持容器密闭。 P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。 P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。 P241+P242+P243 P242 Use only non-sparking tools. 只能使用无火花工具。 P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P302+P352 P302+P352+P332+P313+P362+P364 P303+P361+P353 P305+P351+P338 P305+P351+P338+P337+P313 P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。 P332+P313 P337+P313 P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用 P370+P378 P403+P235 P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECS	KM5480000
Packing Group	III
UN Number	1987 1993
Hazard statements
H226 Flammable liquid and vapour 易燃液体和蒸气 H315 Causes skin irritation 会刺激皮肤 H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment	Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes	3
Storage condition	2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class	3

经由相关异氰酸酯的醇解，合成Teoc-protected 胺。也是羧基和磷酸根基团的保护试剂。

{ALD} Beilstein:4(4)3951

{uni_hamburg} Short: III/35F

{ALF} Carboxyl groups can be protected as 2-(trimethylsilyl)ethyl (TMSE) esters by carbodiimide coupling: Helv. Chim. Acta, 60, 2711 (1977); J. Org. Chem., 62, 93 (1997), from the acid chloride in pyridine: Helv. Chim. Acta, 60, 3039 (1977), or refluxing the acid in THF in the presence of TMS chloride: J. Am. Chem. Soc., 106, 3030 (1984). The TMSE protecting group is useful in peptide synthesis. Cleavage is readily effected with TBAF in DMF or DMSO: Helv. Chim. Acta, 60, 2711 (1977); Bioorg. Med. Chem. Lett., 3, 437 (1993).

{uni_hamburg} Short: EINECS

2916-68-9 H73162 2-(Trimethylsilyl)ethanol
2-三甲基硅基乙醇

化学属性

Mol. Formula	C5H14OSi
Mol. Weight	118.25
Boiling Point	145°C at 760 mmHg
Density	0.825
Refractive index	1.4230 to 1.4250
Flash Point	56 °C - 闭杯
TSCA	No
Solubility	可溶
Melting Point	N/A

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

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2-(Trimethylsilyl)ethanol 2-三甲基硅基乙醇

规格: 95%

化学属性

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