DoMole-安徽敦茂科技

Trimethyl phosphite 三甲氧基磷

规格: 98%

CAS: 121-45-9

产品编号: H73076

MDL: MFCD00008350

品牌: INFI

Chemical Name	Trimethyl phosphite
Synonym	phosphorous acid trimethyl ester P(OMe)3 PHOSPHOROUS ACID TRIMETHYL ESTER 亚磷酸三甲酯溶液 Trimethylfosfit Phosphorigsuretrimethylester Trimethylphosphite,97% 三甲基亞磷三甲羥基亞磷酸 Trimethyl phosphite TRIMETHYL PHOSPHITE Trimethoxyphosphine Phosphonousacidtrimethylester Phosphorous acid trimethyl ester Fosforyn trojmetylowy TrimethyPhosphite Phosphorous acid, trimethyl ester Phosphorigsäuretrimethylester AURORA KA-1230 亚磷酸三甲酯 fosforyntrojmetylowy Trimethoxyfosfin P(OCH3)3 TRIMETHYL PHOSPHITE, 99+%, NMR GRADE TRIMETHYL PHOSPHITE, 99+% TRIMETHYL PHOSPHONATE Trimethyl phosphit
CAS Number	121-45-9
PubChem Substance ID	8472
EC Number	204-471-5
Beilstein Registry Number	956570
MDL Number	MFCD00008350
Chemical Name Translation	三甲氧基磷
Wiswesser Line Notation	1OPO1&O1
InChI	InChI=1S/C3H9O3P/c1-4-7(5-2)6-3/h1-3H3

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ALBRW* Albright & Wilson Inc.  (P.O. Box 26229, Richmond, VA 23260-6229)
   Volume(issue)/page/year: #OPB-3,1984

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >10000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   34,286,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   34,286,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ENVRAL Environmental Research.  (Academic Press, Inc., 1 E. First St.,
   Duluth, MN 55802) V.1-    1967-  Volume(issue)/page/year: 9,1,1975

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1640 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - urogenital system
   Reproductive - Specific Developmental Abnormalities - homeostasis
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   72,119,1984

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1640 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - Central Nervous System
   Reproductive - Specific Developmental Abnormalities - craniofacial
   (including nose and tongue)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   72,119,1984

WGK Germany	3
Hazard Codes	F,T F,Xi Xn
Hazard statements
H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕 H225 Highly flammable liquid and vapour 高度易燃液体和蒸气 H319 Causes serious eye irritation 严重刺激眼睛 H315 Causes skin irritation 会刺激皮肤 H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命 H335 May cause respiratory irritation 可能导致呼吸道刺激 H350 May cause cancer 可能致癌 H340 May cause genetic defects 可能导致遗传性缺陷 H318 Causes serious eye damage 严重伤害眼睛 H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官 H302 Harmful if swallowed 吞食有害 H226 Flammable liquid and vapour 易燃液体和蒸气
Personal Protective Equipment	Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECS	TH1400000
Precautionary statements
P308+P313 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。 P370+P378 P201 Obtain special instructions before use. 使用前获取专门指示。 P403+P235 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P305+P351+P338
Signal word	Danger
UN Number	2329 UN 2329 3/PG 3 UN2329
Risk Statements
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性 R22 Harmful if swallowed 吞咽有害 R10 Flammable 易燃 R41 Risk of serious damage to eyes 有严重损伤眼睛的危险 R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性 R11 Highly flammable 非常易燃 R48/23/24/25 R46 May cause inheritable genetic damage 可能引起遗传基因损害 R45 May cause cancer 可能致癌 R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官 R36 Irritating to eyes 刺激眼睛 R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂 R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥 R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
Safety Statements
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套； S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾； S39 Wear eye/face protection 戴眼睛/面孔保护装置； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）； S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签； S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明； S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Storage condition	Air & Moisture Sensitive 2-8°C
Packing Group	III
Hazard Class	3
Warnings	危化品目录(2015)
Restrict	危险品

{SA} Aldrich MSDS 1 , 1795:C / Corp MSDS 1 (2), 3494:A / FT-IR 1 (1), 910:A / FT-IR 2 (1), 1544:D / FT-NMR 1 (1), 1465:C / IR-Spectra (2), 486:A / IR-Spectra (3), 548:B / NMR-Reference 2 (2), 862:B / RegBook 1 (1), 1093:A / Sax 6 , 2674 / Sigma FT-IR 1 (2), 958:B / Structure Index 1 , 168:C:9 / Vapor Phase 3 , 838:B

{SA} Beil. 1 ,IV,1256

{SA} Fieser 1 ,1233 / Fieser 2 ,439 / Fieser 3 ,315 / Fieser 4 ,541 / Fieser 5 ,717 / Fieser 7 ,393 / Fieser 9 ,490 / Fieser 11 ,570 / Fieser 12 ,536

{uni_hamburg} Short: II/2

Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds

Author: König, E.

Editor: Hellwege, K.-H.; Hellwege, A.M.

Source: Landolt-Börnstein, New Series

Volume: II/2

Year: 1966

ISBN: 3-540-03593-1

ISBN: 978-3-540-03593-0

Internet Resource: DOI:10.1007/b19948

RefComment: 170 figs., XII, 578 pages. Hardcover

Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.

{uni_hamburg} Short: II/25C

Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms

Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.

Editor: Kuchitsu, K.

Source: Landolt-Börnstein, New Series

Volume: II/25C

Year: 2001

Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules

ISBN: 3-540-66774-1

ISBN: 978-3-540-66774-2

Internet Resource: DOI:10.1007/b71431

RefComment: VIII, 481 pages. Hardcover

Abstract: This volume c

121-45-9 H73076 Trimethyl phosphite
三甲氧基磷

化学属性

Mol. Formula	C3H9O3P
Mol. Weight	124.08
Refractive index	n20/D 1.408(lit.)
Boiling Point	110-112°C
Density	1.052
Melting Point	-78 °C (lit.)
Flash Point	82°F
TSCA	Yes
Vapor Density	4.3 (vs air)
Vapor Pressure	17 mmHg ( 20 °C)
Solubility	不溶于水，溶于多数有机溶剂。
Appearance	colorless liq.
Stability	air sensitive

*以上化合物性质及应用等信息仅供参考

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Trimethyl phosphite 三甲氧基磷

规格: 98%

化学属性

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