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Bis(1,5-cyclooctadiene)diiridium(I) dichloride 双(1,5-环辛二烯)氯化铱(I)二聚体

规格: 98%

CAS: 12112-67-3

产品编号: H71177

MDL: MFCD00012414

品牌: INFI

Chemical Name	Bis(1,5-cyclooctadiene)diiridium(I) dichloride
Synonym	1, 1,5-辛二烯氯化铱二聚体 BIS(1,5-CYCLOOCTADIEN)DIIRIDIUM(I)-DICHL ORIDE BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DIC& Bis(1,5-cyclooctadiene)diiridium(I) dichloride CHLORO(1,5-CYCLOOCTADIENE)IRIDATE (I) DIMER CHLORO(1,5-CYCLOOCTADIENE)IRIDIUM(I) DIMER (57%IR) Chlor-(1,5-cyclooctadien)-iridium(I) Dimer Chloro(1,5-cyclooctadiene)iridium(I) dimer Chloro(1,5-cyclooctadiene)iridium(I), dimer,99.9% Chloro(1,5-cyclooctadiene)iridium(I)dimere Chloro-1,5-cyclooctadieneiridium(I)dimer,99% DI-MU-CHLORO-BIS[(1,2,5,6-ETA)-1,5-CYCLOOCTADIENE]DIIRIDIUM IRIDIUM I CYCLOOCTADIENE CHLORIDE [Ir(cod)Cl]2 di-mu-chlorobis[(1,2,5,6-eta)cycloocta-1,5-diene]diiridium 双(1,5-环辛二烯)diiridium(一)二氯化氯代-1,5-环戊二烯铱二聚体
MDL Number	MFCD00012414
EC Number	235-170-7
PubChem Substance ID	87560730
CAS Number	12112-67-3
Beilstein Registry Number	14372408
Chemical Name Translation	双(1,5-环辛二烯)氯化铱(I)二聚体
Reaxys-RN	14372408
InChIKey	ILRJMVBVICHYPJ-UHFFFAOYSA-L
LabNetwork Molecule ID	LN00197889

GHS Symbol

WGK Germany	3
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P305+P351+P338 P305+P351+P338+P337+P313 P332+P313 P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
H315 Causes skin irritation 会刺激皮肤 H319 Causes serious eye irritation 严重刺激眼睛 H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word	Warning
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Codes	Xi
Storage condition	0-10°C 2-8°C

{ALF} In the presence of a phosphite, catalyzes displacements by carbon nucleophiles at the more substituted position in allylic systems: Angew Chem. Int. Ed., 36, 263 (1997); J. Am. Chem. Soc., 120, 8647 (1998).

{ALF}

{ALF} With catalytic amounts of dppp (1,3-Bis(diphenylphosphino)propane, A12931) and Cs2CO3, a transfer hydrogenation system with 2-propanol as the H source can reduce both olefinic double bonds and carbonyl groups; for ɑß-unsaturated ketones, selective reduction to saturated ketones can be achieved: J. Org. Chem., 66, 4710 (2001).

{ALF} Effective catalyst for the reaction of alcohols with vinyl acetate to give vinyl ethers: J. Am. Chem. Soc., 124, 1590 (2002).

{ALF} Catalyst for Miyaura and Hartwig's direct boronylation of arenes with Bis(pinacolato)diboron, L16088: J. Am. Chem. Soc., 124, 390 (2002):

{uni_hamburg} Short: III/10b

{uni_hamburg} Short: EINECS

{ALF} Catalyst precursor for asymmetric hydrogenation: Angew. Chem. Int. Ed., 37, 2897 (1998).

12112-67-3 H71177 Bis(1,5-cyclooctadiene)diiridium(I) dichloride
双(1,5-环辛二烯)氯化铱(I)二聚体

化学属性

Mol. Formula	[IrCl(C8H12)]2
Mol. Weight	672
Melting Point	202 - 208 °C (dec.)(lit.)
Solubility	Soluble in chloroform, toluene. Slightly soluble in acetone, alcohol.
TSCA	No
Density	1.422
Appearance	red to orange pwdr.
Redox	Reduction

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Bis(1,5-cyclooctadiene)diiridium(I) dichloride 双(1,5-环辛二烯)氯化铱(I)二聚体

规格: 98%

化学属性

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