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Tetramethoxysilane 原硅酸四甲酯

规格: 98%
CAS: 681-84-5
产品编号: H70388
MDL: MFCD00008341
品牌: INFI
Chemical NameTetramethyl orthosilicate
Synonym Dynasil M KBM 04 MSP 150 Methyl Silicate 39 Methyl orthosilicate Methyl silicate ((MeO)4Si) Orthokieselsäuretetramethylester SILICON TETRAMETHOXIDE Silicic acid (H4SiO4), tetramethyl ester Silicic acid, methyl ester of ortho- Silicic acid, methyl ester of ortho- Silicic acid, tetramethyl ester Silicon methoxide (Si(OMe)4) TETRAMETHOXYSILANE TL 190 TMOS Tetramethoxy silane Tetramethoxysilane Tetramethyl Orthosilicate {Chemicalbook} methylsilicate[(meo)4si] silicic acid tetramethyl ester silicicacid(h4sio4),tetramethylester {} {Chemicalbook} methylorthosilicate {} {} {uni_hamburg} Tetramethylorthosilikat {} {} {} {Chemicalbook {} {} {} {un
CAS Number681-84-5
PubChem Substance ID87576485
EC Number211-656-4
Beilstein Registry Number1,287
MDL NumberMFCD00008341
Reaxys-RN1699658
Chemical Name Translation正硅酸甲酯
Wiswesser Line Notation1O-SI-O1&O1&O1
LabNetwork Molecule IDLN00193983
InChIInChI=1S/C4H12O4Si/c1-5-9(6-2,7-3)8-4/h1-4H3
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, US

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 39(4),86,1974

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - acute pulmonary edema
   Kidney, Ureter, Bladder - changes in tubules (including acute renal failure,
   acute tubular necrosis)
REFERENCE :
   30ZNA5 "Dangerous Properties of Industrial Materials," Sax, N.I., New York,
   Van Nostrand Reinhold, 1980  Volume(issue)/page/year: 3,935,1968

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Kidney, Ureter, Bladder - changes in tubules (including acute renal failure,
   acute tubular necrosis)
REFERENCE :
   30ZNA5 "Dangerous Properties of Industrial Materials," Sax, N.I., New York,
   Van Nostrand Reinhold, 1980  Volume(issue)/page/year: 3,935,1968

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE

WGK Germany3
Hazard Codes T+ 6.1
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H330 Fatal if inhaled 吸入致命
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    RTECSVV9800000
    Precautionary statements
    • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P305+P351+P338
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P304+P340+P310
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
    • P302+P352+P332+P313+P362+P364
    • P305+P351+P338+P310
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P303+P361+P353
    • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P370+P378
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
    • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P332+P313
    • P233 Keep container tightly closed. ?保持容器密闭。
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P308+P311
      Signal word Danger Warning
      UN Number UN 2606 6.1/PG 1 UN2606 2606
      Risk Statements
      • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      • R26 Very toxic by inhalation 吸入极毒
      • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
      • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
      • R10 Flammable 易燃
        Safety Statements
        • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
        • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
        • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
        • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
        • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
          Storage condition 200.0 Flammables area Moisture Sensitive 密封阴凉干燥保存。对湿度敏感 阴凉干燥保存。
          Packing GroupI
          Hazard Class6.1/3
          Warnings 危化品目录(2015)
          Restrict 危险品
        • 合成其他硅烷产品,用于生产耐热涂料、耐化学作用的涂料、有机硅溶剂和精密铸造用粘合剂等,在有机硅粘合剂和密封胶中作交联组份。
        • {uni_hamburg} Short: II/25C
        • {ALD} Beilstein:1,287
        • {uni_hamburg} Short: II/5
        • 681-84-5 H70388 Tetramethoxysilane
原硅酸四甲酯

          化学属性

          Mol. FormulaC4H12O4Si
          Mol. Weight152.22
          Refractive index1.3670 to 1.3700
          Boiling Point122°C
          Density1.032
          Melting Point4-5°C
          Flash Point29°C(lit.)
          TSCAYes
          Vapor Density5.25 (vs air)
          Vapor Pressure3.35 psi ( 20 °C)
          Solubility水解
          Stability对湿度敏感
          Appearance colorless liq.

          *以上化合物性质及应用等信息仅供参考