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Bismuth chloride 氯化铋

规格: 98%

CAS: 7787-60-2

产品编号: H63141

MDL: MFCD00003461

品牌: INFI

Chemical Name	Bismuth Trichloride
Synonym	Bismuth chloride {LY} Bismuth chloride {} {LY} Bismuth chloride {} {} {LY} Bismuth chloride {} {} {} {LY} Bismuth chloride {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number	7787-60-2
PubChem Substance ID	87561573
EC Number	232-123-2
MDL Number	MFCD00003461
Merck Number	1262
Beilstein Registry Number	2384789
Chemical Name Translation	氯化铋
Reaxys-RN	3903092
LabNetwork Molecule ID	LN00196712
Canonical SMILES	Cl[Bi](Cl)Cl

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3334 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 30(6),16,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 30(6),16,1986

WGK Germany	2
Hazard Codes	Xi
Hazard statements
H315 Causes skin irritation 会刺激皮肤 H319 Causes serious eye irritation 严重刺激眼睛 H303 May be harmfully swallowed 吞食可能有害
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RTECS	EB2690000
Precautionary statements
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P302+P352+P332+P313+P362+P364 P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。 P332+P313 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P305+P351+P338 P305+P351+P338+P337+P313 P302+P350 P337+P313
Signal word
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）； S20 When using do not eat or drink 使用时，不得进食，饮水； S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置； S3 Keep in a cool place 保存在阴凉处； S36 Wear suitable protective clothing 穿戴适当的防护服；
UN Number	3260 UN3260
Risk Statements
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition	Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store
Packing Group	III
Hazard Class	8

制造铋盐，有机反应催化剂，高纯材料。

{ALFA} For catalysis of Diels-Alder and hetero Diels-Alder reactions, see: J. Org. Chem., 62, 4880 (1997); Tetrahedron Lett., 39, 1161 (1998).

{uni_hamburg} Short: II/25A

{ALFA} Catalyzes the addition of 1,3-dicarbonyl compounds to Michael acceptors under solvent-free conditions with microwave irradiation: Tetrahedron Lett., 38, 1449 (1997).

{ALD} Merck: 14,1262

{ALFA} Lewis acid catalyst which promotes the rearrangement of acetanilides to o-amino ketones: Tetrahedron Lett., 3217 (1976).

{ALFA} For a brief feature on Bi(III) catalysts, see: Synlett, 1194 (2001). For a review of their use in acylation and sulfonylation reactions, see: Synlett, 181 (2002).

{ALFA} Promotes the chemoselective deprotection of N-Boc amino acids and peptides: Tetrahedron Lett., 47, 389 (2006).

{ALFA} Silyl enol ethers can be ɑ-acylated with acyl chlorides in the presence of a catalytic amount of BiCl3 and NaI or ZnI2; other Lewis acids such as ZnCl2 were less effective: J. Org. Chem., 61, 3885 (1996).

{ALFA} Arenes undergo sufonylation by heating with arenesulfonyl chlorides in the presence of BiCl3 (5 mol%) and triflic acid (10 mol%) to give high yields of mixed diaryl sulfones; neither BiCl3 nor TfOH alone is effective: Tetrahedron Lett., 40, 9233 (1999).

化学属性

Mol. Formula	BiCl3
Mol. Weight	315.34
Boiling Point	447 ºC
Melting Point	230 - 232 ºC
Density	4.73
TSCA	Yes
Solubility	Soluble in HCl, HNO3, acetone, ethyl acetate. Insoluble in alcohol. Decomposed by water to BiOCl
Flash Point	430°C
Appearance	white xtl.
Stability	moisture sensitive

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Bismuth chloride 氯化铋

规格: 98%

化学属性

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