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Triisopropylchlorosilane 三异丙基氯硅烷

规格: 97%

CAS: 13154-24-0

产品编号: H59263

MDL: MFCD00009656

品牌: INFI

Chemical Name	Triisopropylsilyl chloride
MDL Number	MFCD00009656
Synonym	Chlorotriisopropylsilane, 97+% Chlorotriisopropylsilane, Triisopropylsilyl chloride TIPSCI TIPSCl TRIISOPROPYLSILYL CHLORIDE Triisopropylsilyl chloride Chlorotriisopropylsilane 三异丙基氯甲硅烷
CAS Number	13154-24-0
Beilstein Registry Number	1737446
PubChem Substance ID	87576875
EC Number	250-023-7
Alfabeta Name	TRIISOPROPYLSILYLCHLORIDE
Reaxys-RN	1737446
Chemical Name Translation	三异丙基氯硅烷
InChIKey	KQIADDMXRMTWHZ-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00007870

GHS Symbol

Packing Group	II
UN Number	2987 UN 2987 8/PG 2 UN2987
Risk Statements
R34 Causes burns 会导致灼伤
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护；
Storage condition	Moisture Sensitive
WGK Germany	3
Hazard statements
H227 Combustible liquid 可燃液体 H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment	Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。 P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P304+P340 P305+P351+P338 P305+P351+P338+P310 P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。 P370+P378 P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word	Danger
Hazard Codes	8 C
Warnings	IRRITANT
Hazard Class	8
RTECS	MB9865000

{ALF} For a comprehensive review of the TIPS group in organic chemistry, see: Chem. Rev., 95, 1009 (1995). See also Triisopropylsilyl trifluoromethanesulfonate, B21127.

{ALF} Cleavage is usually accomplished by treatment with F-: J. Org. Chem., 51, 4941 (1986); see Tetra-n-butylammonium fluoride, A10588. Alternative methods include dilute HCl: Tetrahedron Lett., 2865 (1974), or 80% AcOH: J. Carbohydr., Nucleosides, Nucleotides, 3, 197 (1976).

{ALF} Reagent for the protection of alcohols as triisopropylsilyl (TIPS) ethers. See Appendix 4. Methods of introduction include imidazole in DMF: Tetrahedron Lett., 2865 (1974), or imidazole/DMAP: Chem. Lett., 41 (1987). Also useful for N-protection. The steric bulk of TIPS makes it useful as a regio- and stereodirecting group, allowing selective protection of primary hydroxyl in the presence of secondary: Tetrahedron Lett., 2865 (1974). TIPS ethers are more resistant to acidic hydrolysis than TBDMS ethers, but less so than tert-butyldiphenylsilyl (TBDPS) ethers. However, they are more resistant to basic hydrolysis than either TBDMS or TBDPS derivatives: J. Org. Chem., 45, 4797 (1980); 49, 3239 (1984); Tetrahedron Lett., 24, 3455 (1983).

13154-24-0 H59263 Triisopropylchlorosilane
三异丙基氯硅烷

化学属性

Mol. Formula	C9H21ClSi
Mol. Weight	193
Density	0.901
Refractive index	1.4520 to 1.4540
Flash Point	62°C(lit.)
TSCA	No
Boiling Point	198
Vapor Pressure	1.16 mmHg ( 20 °C)
pH	:A

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Triisopropylchlorosilane 三异丙基氯硅烷

规格: 97%

化学属性

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