DoMole-安徽敦茂科技

Rhodium(II) acetate dimer 二聚醋酸铑

规格: 98%, 46% Rh

CAS: 15956-28-2

产品编号: H57636

MDL: MFCD00003538

品牌: INFI

Chemical Name	Rhodium(II) Acetate Dimer
Synonym	Dirhodium tetraacetate {LY} Dirhodium tetraacetate {} {LY} Dirhodium tetraacetate {} {} {LY} Dirhodium tetraacetate {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY
MDL Number	MFCD00003538
PubChem Substance ID	24852229
CAS Number	15956-28-2
EC Number	240-084-8
Reaxys-RN	14201302
Beilstein Registry Number	14201302
Chemical Name Translation	乙酸铑(II)二聚体
Canonical SMILES	O1=C([O-][Rh+2]234O=C([O-][Rh+2]14(O=C([O-]2)C)[O-]C(=O3)C)C)C

GHS Symbol

TYPE OF TEST            : LD10 - Lethal Dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 115 mg/kg
TOXIC EFFECTS :
   Tumorigenic - active as anti-cancer agent
REFERENCE :
   JMCMAR Journal of Medicinal Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC
   20037)  V.6-    1963-  Volume(issue)/page/year: 20,943,1977

WGK Germany	3
Personal Protective Equipment	Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RTECS	VI9361000
Hazard Codes	Xi
Safety Statements
S15 Keep away from heat 远离热源； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性 R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Signal word	Warning
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P305+P351+P338
Storage condition	2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

烯烃的环丙烷化，同源催化剂，高效催化剂，用于形成叶立德。

{ALF} Catalyst for various cyclization reactions involving ɑ-diazo carbonyl groups. Promotes the formation of macrocyclic lactones via intramolecular cyclopropanation and carbon-hydrogen insertion: J. Am. Chem. Soc., 117, 7181 (1995). For a brief feature on uses of the reagent in synthesis, see: Synlett, 3169 (2005).

{SA} Sugimura, T.; Mori, A. et. al. Tetrahedron Asymmetry 14 , 881, (2003)

{SA} Zhu, S.; Liao, Y.; Zhu, S. Org. Lett. 6 , 377, (2004) 摘要

{SA} Beil. 2 ,124

15956-28-2 H57636 Rhodium(II) acetate dimer
二聚醋酸铑

化学属性

Mol. Formula	C8H12O8Rh2
Mol. Weight	441.99
Melting Point	205 °C
TSCA	No
Solubility	Slightly soluble in ethanol
Density	1.422
Appearance	greenish-black xtl.

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Rhodium(II) acetate dimer 二聚醋酸铑

规格: 98%, 46% Rh

化学属性

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