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Antimony(III) chloride 氯化锑(III)

规格: 99%

CAS: 10025-91-9

产品编号: H54962

MDL: MFCD00011212

品牌: INFI

Chemical Name	Antimony Trichloride
Synonym	Antimony trichloride Antimonous chloride Trichlorostibine Antimon-III-chlorid Antimony chloride; Antimonous chloride; Antimony butter; Trichlorostibine; Antimony(III) chloride; Antimony(III) trichloride; C.I. 77056; Trichloroantimony trichloro-stibine Butter of antimony 氯化锑(III) Trichloroantimony Stibine, trichloro- C.I. 77056 Trichlorure d'antimoine Antimony(III) trichloride Chlorid antimonity 三氯化锑 Antimony(III) chloride antimony (III) chloride Antimonio (tricloruro di) Antimon(III)chlorid Antimony chloride (Sb2Cl6) Antimonous chloride; Antimony(III) chloride; Trichlorostibine Antimon(III)-chlorid Antimony Butter Antimoontrichlride
CAS Number	10025-91-9
PubChem Substance ID	24860477
EC Number	233-047-2
MDL Number	MFCD00011212
Merck Number	14,707
Chemical Name Translation	三氯化锑
Wiswesser Line Notation	SB G3
LabNetwork Molecule ID	LN00194131

GHS Symbol

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 73 mg/m3
TOXIC EFFECTS :
   Behavioral - anorexia (human)
   Lungs, Thorax, or Respiration - other changes
   Gastrointestinal - other changes
REFERENCE :
   BJIMAG British Journal of Industrial Medicine.  (British Medical Journal,
   Box 560B, Kennebunkport, ME 04046)  V.1-    1944-  Volume(issue)/page/year:
   23,318,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 525 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   MarJV# Personal Communication from J.V. Marhold, VUOS, 539-18, Pardubice,
   Czechoslavakia, Mar. 29, 1977  Volume(issue)/page/year: 29MAR1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 13 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,23,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 574 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - spastic paralysis with or without sensory
   change
   Gastrointestinal - peritonitis
   Gastrointestinal - necrotic changes
REFERENCE :
   HYSAAV Hygiene and Sanitation (USSR).  English translation of GISAAA.
   (Springfield, VA)  1964-71. Discontinued.  Volume(issue)/page/year:

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 10 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 77,109,1980

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 2500 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 264,163,1991

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 44 mg/kg
SEX/DURATION            : female 1-22 day(s) after conception
                          lactating female 22 day(s) post-birth
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight
   gain)
REFERENCE :
   TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis.  (Alan R. Liss, Inc.,
   41 E. 11th St., New York, NY 10003)  V.1-    1980- Volume(issue)/page/year:
   7,491,1987

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 4400 ug/kg
SEX/DURATION            : female 1-22 day(s) after conception
                          lactating female 22 day(s) post-birth
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - delayed effects
REFERENCE :
   TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis.  (Alan R. Liss, Inc.,
   41 E. 11th St., New York, NY 10003)  V.1-    1980- Volume(issue)/page/year:
   7,491,1987

WGK Germany	3
Hazard Codes	C,N
Hazard statements
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤 H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment	Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECS	CC4900000
Precautionary statements
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。 P273 Avoid release to the environment. 避免释放到环境中。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P305+P351+P338
Signal word
Safety Statements
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
UN Number
Risk Statements
R51/53 R34 Causes burns 会导致灼伤
Storage condition	Moisture Sensitive
Packing Group	II
Warnings	危化品目录(2015)
Restrict	危险品

{SA}

Merck 14 ,707 / Merck 14 ,708

{SA}

Fieser 8 ,19

{SA}

Aldrich MSDS 1 , 134:B / Corp MSDS 1 (1), 287:D / RegBook 1 (3), 3327:D / Sax 6 , 300

{uni_hamburg} Short: II/25A

Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules

Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.

Editor: Kuchitsu, K.

Source: Landolt-Börnstein, New Series

Volume: II/25A

Year: 1998

Keyword: Free Polyatomic Molecules; Inorganic Molecules; Molecules

ISBN: 3-540-61713-2

ISBN: 978-3-540-61713-6

Internet Resource: DOI:10.1007/b59072

RefComment: VII, 359 pages. Hardcover

Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure o

{ALF} Mild Lewis acid catalyst.

{ALF} Preferred catalyst for fluoro-Pummerer reaction with DAST (Diethylaminosulfur trifluoride, A11992) for the formation of ɑ-fluoro thioethers from sulfoxides: Tetrahedron Lett., 29, 5729 (1988); J. Org. Chem., 55, 4757 (1990); Org. Synth. Coll., 9, 446 (1998). Direct conversion of thioethers to the ɑ-fluoro analogues has also been reported: J. Org. Chem., 58, 3800 (1993).

{ALF} Superior to other Lewis acids for promoting the palladium(0)-catalyzed conjugate arylation of ɑß-unsaturated ketones and aldehydes with tetraphenyl borate and arylboronic acids: J. Org. Chem., 60, 883 (1995). Effective catalyst for conversion of epoxides to thiiranes with (NH4)2SCN: Indian J. Chem., 38B, 605 (1999).

10025-91-9 H54962 Antimony(III) chloride
氯化锑(III)

化学属性

Mol. Formula	Cl3Sb
Mol. Weight	228
Melting Point	73.4°C
Density	3.14
TSCA	Yes
Boiling Point	283°C
Solubility	Soluble in water with hydrolysis to SbOCl. Soluble in HCl solution, alcohol, benzene, carbon disulfide, dioxane, chloroform, ether, acetone, carbon tetrachloride. Insoluble in organic bases
Vapor Density	7.9 (vs air)
Vapor Pressure	1 mmHg ( 49 °C)
Appearance	off-white xtl.
Stability	moisture sensitive

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

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Antimony(III) chloride 氯化锑(III)

规格: 99%

化学属性

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