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Dimethyl (2-Oxopropyl)phosphonate 丙酮基膦酸二甲酯

规格: 95%
CAS: 4202-14-6
产品编号: H46956
MDL: MFCD00008769
品牌: INFI
Chemical NameDimethyl acetylmethylphosphonate
CAS Number4202-14-6
EC Number224-110-5
Beilstein Registry Number1766218
MDL NumberMFCD00008769
Synonym Dimethyl acetonylphosphonate {LY} Dimethyl acetonylphosphonate {} {LY} Dimethyl acetonylphosphonate {} {} {LY} Dimethyl acetonylphosphonate {} {} {} {LY} Dimethyl acetonylphosphonate {} {} {} {} {LY} Dimethyl acetonylphosphonate {} {} {} {} {} {LY} Dimethyl acetonylphosphonate {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate {} {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate {} {} {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID77872
Chemical Name Translation2-氧代丙基膦酸二甲酯
Reaxys-RN1766218
InChIKeyUOWIYNWMROWVDG-UHFFFAOYSA-N
LabNetwork Molecule IDLN00009226
InChIInChI=1S/C5H11O4P/c1-5(6)4-10(7,8-2)9-3/h4H2,1-3H3
Canonical SMILESCC(CP(OC)(OC)=O)=O
GHS Symbol
Signal word Warning
WGK Germany3
Safety Statements
    Risk Statements
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      Precautionary statements
      • P201 Obtain special instructions before use. 使用前获取专门指示。
      • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
      • P301+P312
      • P302+P352
      • P304+P312
      • P304+P340
      • P305+P351+P338
      • P308+P313
      • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
      • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
      • P330 Rinse mouth. 漱口
      • P332+P313
      • P337+P313
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      • P403+P233
      • P403+P235
      • P405 Store locked up. 上锁保管。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US)
        Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
        Hazard statements
        • H227 Combustible liquid 可燃液体
        • H302 Harmful if swallowed 吞食有害
        • H315 Causes skin irritation 会刺激皮肤
        • H319 Causes serious eye irritation 严重刺激眼睛
        • H332 Harmful if inhaled 吸入有害
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
        • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
          Hazard Codes Xi
        • {ALD} Beilstein: 4,IV,3604
        • {ALF} Successive treatment with NaH and n-BuLi gives the dianion which can be alkylated or acylated on the terminal position: see. e.g.: Synth. Commun., 22, 219 (1992); J. Chem. Soc., Perkin 1, 2259 (1998).
        • {ALF} For use of ß-ketophosphonates in an annulation sequence for building a cyclohexadienone ring onto a cyclic ketone, see: Synthesis, 855 (1982):
        • {ALF} Horner-Wadsworth-Emmons precursor of ɑß-unsaturated ketones.
          • 4202-14-6 H46956 Dimethyl (2-Oxopropyl)phosphonate 丙酮基膦酸二甲酯

          化学属性

          Mol. FormulaC5H11O4P
          Mol. Weight166.11
          Density1.202
          Boiling Point227°C at 760 mmHg
          Refractive index1.4380 to 1.4410
          Flash Point93.4°C
          TSCANo

          *以上化合物性质及应用等信息仅供参考

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