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Tris(dimethylamino)phosphine 三(二甲胺基)膦

规格: 99%

CAS: 1608-26-0

产品编号: H42476

MDL: MFCD00008301

品牌: INFI

Chemical Name	Hexamethylphosphorous Triamide
CAS Number	1608-26-0
Synonym	N,N,N',N',N'',N''-Hexamethylphosphinetriamine {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetriamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexamethylphosphinetr
MDL Number	MFCD00008301
EC Number	216-534-4
Beilstein Registry Number	4(4)274
PubChem Substance ID	87577088
Reaxys-RN	906778
Chemical Name Translation	三(二甲胺基)膦
LabNetwork Molecule ID	LN00226609
InChI	InChI=1S/C6H18N3P/c1-7(2)10(8(3)4)9(5)6/h1-6H3
Canonical SMILES	CN(C)P(N(C)C)N(C)C

GHS Symbol

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 212,193,1989

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - hamster Kidney
DOSE/DURATION           : 2500 ug/L
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1947-  Volume(issue)/page/year:
   38,418,1978

Signal word	Danger Warning
WGK Germany	3
Safety Statements
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）； S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
R45 May cause cancer 可能致癌 R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性 R46 May cause inheritable genetic damage 可能引起遗传基因损害 R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用 R10 Flammable 易燃
Precautionary statements
P201 Obtain special instructions before use. 使用前获取专门指示。 P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。 P233 Keep container tightly closed. ?保持容器密闭。 P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。 P241+P242+P243 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。 P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P301+P312+P330 P302+P352+P312+P362+P364 P303+P361+P353 P304+P340+P312 P305+P351+P338 P305+P351+P338+P337+P313 P308+P313 P332+P313 P337+P313 P370+P378 P403+P235 P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
H226 Flammable liquid and vapour 易燃液体和蒸气 H340 May cause genetic defects 可能导致遗传性缺陷 H350 May cause cancer 可能致癌
Personal Protective Equipment	Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
RTECS	TH3390000
Packing Group	III
UN Number	1993 UN 1993 3/PG 3 UN1993
Storage condition	-20°C, stored under nitrogen {LY} -20°C, stored under nitrogen 0-10 0-10°C Air Sensitive Store at RT. {} {LY} -20°C, stored under nitrogen {} {} {LY} -20°C, stored under nitrogen {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {L
Hazard Codes	T T,Xi,Xn Xn
Hazard Class	3

Reagent combination with CCl4 for the conversion of hydroxyl groups to the corresponding chlorides; hydroxyl group activation; dehydrations.

{ALF} Has also been used for a variety of other reductions including that of ozonolysis intermediates: Helv. Chim. Acta, 50, 2387 (1967), and of primary alkyl nitro compounds to nitriles: Synthesis, 36 (1979). Bromohydrins can be converted to alkenes, by reductive elimination from their triflate esters: J. Am. Chem. Soc., 102, 1433 (1980):

{ALF} Reacts with BrCCl3 to give dichloromethylenephosphorane Cl2C=PPh3, which undergoes Wittig reaction with aldehydes to give 1,1-dichloroalkenes, giving better results than the CCl4/PPh3 combination: Tetrahedron Lett., 1237, 1239 (1977); Synthesis, 554 (1980). Similarly, with Br2CF2, the CF2 group can be transferred to both aldehydes and ketones: J. Fluorine Chem., 1, 123 (1971); Synth. Commun., 3, 197 (1973).

{ALF} Reduces aromatic aldehydes to symmetrical epoxides in good yield: J. Am. Chem. Soc., 85, 1884 (1963). Both cis- and trans-isomers are formed. For list of examples, see: Org. Synth. Coll., 5, 358 (1973). Under suitable conditions, reaction of the intermediate with a second aldehyde can lead to mixed deoxybenzoins or diaryl enamines: Synthesis, 225 (1991).

{TRC} Ryu, H., et al.: J. Mat. Sci., 41, 8265 (2006),

{uni_hamburg} Short: II/2

{uni_hamburg} Short: II/25D

1608-26-0 H42476 Tris(dimethylamino)phosphine
三(二甲胺基)膦

化学属性

Mol. Formula	C6H18N3P
Mol. Weight	163.21
Density	0.898
Refractive index	1.4640 to 1.4670
Boiling Point	160.3°C at 760 mmHg
Flash Point	27°C
TSCA	Yes
Melting Point	-44°C
Solubility	起反应
Stability	对空气敏感;热和湿度敏感
Appearance	yellow liq.

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

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Tris(dimethylamino)phosphine 三(二甲胺基)膦

规格: 99%

化学属性

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