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(2S,3S)-(+)-1,4-Bis(diphenylphosphino)-2,3-O-isopropylidene-2,3-butanediol (+)-异丙烯-2,3-二羟-1,4-双二丙基膦丁烷

规格: 98%

CAS: 37002-48-5

产品编号: H33388

MDL: MFCD00009760

品牌: INFI

Chemical Name	(+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane
Synonym	(+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane (4S-反式)-[(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(亚甲基)]双(二苯基膦) (+)-1,4-双(二苯基膦)-1,4-二脱氧-2,3-O-异亚丙基-D-苏糖醇 (+)-DIOP (4S,5S)-4,5-双(二苯基膦甲基)-2,2-二甲基-1,3-二氧戊环 (4S-反式)-[(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(亚甲基)]双(二苯基膦) (S,S)-DIOP (+)-2,3-O-异丙烯基-2,3-二羟基-1,4-双(二苯基膦)丁烷 (+)-DIOP (+)-1,4-双(二苯基膦)-1,4-二脱氧-2,3-O-异亚丙基-D-苏糖醇 (4S,5S)-4,5-双(二苯基膦甲基)-2,2-二甲基-1,3-二氧戊环 (4S-反式)-[(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(亚甲基)]双(二苯基膦) (S,S)-DIOP
MDL Number	MFCD00009760
PubChem Substance ID	87564055
Beilstein Registry Number	1630280
CAS Number	37002-48-5
EC Number	253-307-9
Reaxys-RN	5148912
Chemical Name Translation	异丙烯-2,3-二羟-1,4-双二丙基膦丁烷

GHS Symbol

WGK Germany	3
Precautionary statements
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P305+P351+P338 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P302+P352+P332+P313+P362+P364 P305+P351+P338+P337+P313
Hazard statements
H315 Causes skin irritation 会刺激皮肤 H319 Causes serious eye irritation 严重刺激眼睛 H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes	Xi
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
Signal word
Safety Statements

Risk Statements
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition	Air Sensitive

{SA}

Morimoto, T. et al. Tetrahedron Asymmetry 6 , 23, (1995)

{SA}

Morimoto, T. at al. Tetrahedron Asymmetry 6 , 75, (1995)

{SA}

Matsumoto, Y. et al. Tetrahedron 50 , 335, (1994)

{SA}

Sato, Y. et al. Tetrahedron 50 , 371, (1994)

{SA}

Gladiali, S. Pinna, L. Tetrahedron Asymmetry 1 , 693, (1990)

{SA}

Fieser 4 ,273 / Fieser 5 ,360 / Fieser 6 ,309 / Fieser 9 ,259 / Fieser 11 ,277 / Fieser 13 ,153

{SA}

Aldrich MSDS 1 , 1121:B / Corp MSDS 1 (1), 2037:A / FT-IR 2 (2), 3322:C / FT-IR 1 (2), 542:A / FT-NMR 1 (2), 1662:B / NMR-Reference 2 (2), 879:D / RegBook 1 (2), 2267:J / Sigma FT-IR 1 (2), 671:B / Structure Index 1 , 355:E:3

{ALFA} Ligand for the in situ preparation of chiral hydrogenation catalysts: J. Am. Chem. Soc., 94, 6429 (1972); Helv. Chim. Acta, 57, 2487 (1974); J. Org. Chem., 44, 3741 (1979).

{ALF} Ligand for the in situ preparation of chiral hydrogenation catalysts: J. Am. Chem. Soc., 94, 6429 (1972); Helv. Chim. Acta, 57, 2487 (1974); J. Org. Chem., 44, 3741 (1979).

37002-48-5 H33388 (2S,3S)-(+)-1,4-Bis(diphenylphosphino)-2,3-O-isopropylidene-2,3-butanediol
(+)-异丙烯-2,3-二羟-1,4-双二丙基膦丁烷

化学属性

Mol. Formula	C31H32O2P2
Mol. Weight	498.55
Melting Point	87-91°C
TSCA	No
Appearance	white pwdr.
Stability	air sensitive
Density	1.0

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

(2S,3S)-(+)-1,4-Bis(diphenylphosphino)-2,3-O-isopropylidene-2,3-butanediol (+)-异丙烯-2,3-二羟-1,4-双二丙基膦丁烷

规格: 98%

化学属性

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