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1-(Trimethylsilyl)imidazole N-三甲基硅烷基咪唑

规格: 98%

CAS: 18156-74-6

产品编号: H19223

MDL: MFCD00005280

品牌: INFI

Chemical Name	N-(Trimethylsilyl)Imidazole
CAS Number	18156-74-6
Alfabeta Name	TRIMETHYLSILYLIMIDAZOLE 1()-
MDL Number	MFCD00005280
Synonym	1-(Trimethylsilyl)-1H-imidazole 1-(Trimethylsilyl)imidazole 1-(三甲基硅基)咪唑 N-(Trimethylsilyl)imidazole N-三甲基硅烷基咪唑 NSC 139860 TMSI TSIM Trimethylimidazosilane
Beilstein Registry Number	606148
EC Number	242-040-3
PubChem Substance ID	87576564
Reaxys-RN	606148
Chemical Name Translation	N-(三甲基硅基)咪唑
Wiswesser Line Notation	T5N CNJ A-SI-1&1&1
LabNetwork Molecule ID	LN00117274
InChIKey	YKFRUJSEPGHZFJ-UHFFFAOYSA-N

GHS Symbol

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1000 mg/kg/I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   54,495,1975

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 750 mg/kg
TOXIC EFFECTS :
   Immunological Including Allergic - decreased immune response
REFERENCE :
   StoGD# Personal Communication from G.D. Stoner, Dept. of Community Medicine,
   School of Medicine, Univ. of California, La Jolla, CA 92037, May 25, 1975 
   Volume(issue)/page/year: 27MAY1975

Warnings	MOISTURE SENSITIVE, FLAMMABLE
WGK Germany	3
RTECS	NI8700000
Packing Group	II
UN Number	1993
Risk Statements
R11 Highly flammable 非常易燃 R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S33 Take precautionary measures against static discharges 对静电采取预防措施； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S37 Wear suitable gloves 戴适当手套； S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Storage condition	Moisture Sensitive 0-10 充氮或充氩保护 0-10°C 储存温度2-8°C
Signal word	Danger
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。 P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。 P241+P242+P243 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P302+P352+P332+P313+P362+P364 P303+P361+P353 P305+P351+P338 P305+P351+P338+P337+P313 P332+P313 P337+P313 P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用 P370+P378 P403+P235 P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
H315 Causes skin irritation 会刺激皮肤 H335 May cause respiratory irritation 可能导致呼吸道刺激 H225 Highly flammable liquid and vapour 高度易燃液体和蒸气 H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment	Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes	3 F;Xi
Hazard Class	3

甲硅烷基化试剂，在氨基存在的条件下保护羟基基团。抗菌素中间体。

{ALD} Beilstein: 23,V,4,456

{uni_hamburg} Short: III/35F

{ALF} Powerful silylating agent (see Appendix 4) for a wide range of functional groups. O-Silylation in the presence of TBAF (0.02 equiv.) occurs under very mild conditions: Tetrahedron Lett., 35, 8409 (1994).

{TRC} Shin, H. et al.: Chromatographia, 63, 77 (2006); Birkemeyer, C. et al.: J. Chrom., 993, 89 (2003);

{SNA}

18156-74-6 H19223 1-(Trimethylsilyl)imidazole N-三甲基硅烷基咪唑

化学属性

Mol. Formula	C6H12N2Si
Mol. Weight	140
Boiling Point	93-94
TSCA	T
Density	0.956
Refractive index	1.4740 to 1.4780
Flash Point	5°C(lit.)
Melting Point	-42°C
Solubility	分解

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

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1-(Trimethylsilyl)imidazole N-三甲基硅烷基咪唑

规格: 98%

化学属性

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