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(Methylcyclopentadienyl)manganese(I) tricarbonyl 2-甲基环戊二烯三羰基锰

规格: 98%

CAS: 12108-13-3

产品编号: H17856

MDL: MFCD00001426

品牌: INFI

Chemical Name	(Methylcyclopentadienyl)Manganese(I) Tricarbonyl
Synonym	Manganese, tricarbonyl[(1,2,3,4,5η)-1-methyl-2,4-cyclopentadien-1-yl]- {uni_hamburg} Manganese, tricarbonyl[(1,2,3,4,5-h)-1-methyl-2,4-cyclopentadien-1-yl]- π-Methylcyclopentadienylmanganese tricarbonyl { Hitec 3000 methylc Combustion improver -2 Methylcyclopentadienyl manganese tricarbonyl (Methylcyclopentadienyl)tricarbonylmanganese Ethyl MMT MCMT MMT NSC 22316 Tricarbonyl(2-methylcyclopentadienyl)manganese Methylcyclopentadienylmangan-tricarbonyl Manganese, tricarbonyl((1,2,3,4,5-η)-1-methyl-2,4-cyclopentadien-1-yl)- Tricarbonyl(methyl-π-cyclopentadienyl)manganese Manganese methylcyclopentadienyl tricarbonyl Manganese, tricarbonyl(methyl-p-cyclopentadienyl)- Tricarbonyl(methyl-p-cyclopentadienyl)manganese 2-Methylcyclopentadienylmanganese tricarbonyl (Methylcyclopentadienyl)tricarbonylmanganese 2-甲基环戊二烯三羰基锰 Tricarbonyl(η5-methylcyclopentadienyl)manganese(I) Tricarbonyl(methyl-π-cyclopentadienyl)manganese {u Manganese, tricarbonyl(methylcyclopentadienyl)- NSC 22316 Manganese, (methylcyclopentadienyl)tricarbony Tricarbonyl(h5-methylcyclopentadienyl)manganese(I) Tricarbonyl(2-methylcyclopentadienyl)manganese Methylcyclopentadienylmanganese tricarbonyl Tricarbonyl(h5-methylcyclopentadienyl)manganese Tricarbonyl(η5-methylcyclopentadienyl)manganese Tricarbonyl(methylcyclopentadienyl)manganese Methylcymantrene Manganese, tricarbonyl[(1,2,3,4,5-η)-1-methyl-2,4-cyclopentadien-1-yl]- Tricarbonyl(η⁵-methylcyclopentadienyl)manganese Antiknock-33 CI-2
PubChem Substance ID	24859093
EC Number	235-166-5
MDL Number	MFCD00001426
CAS Number	12108-13-3
Merck Number	14,6223
Chemical Name Translation	2-甲基环戊二烯三羰基锰
Wiswesser Line Notation	L5J A1-MN-VHVHVH

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 665 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TMMT** "The Toxicology of Methylcyclopentadienyl Manganese Tricarbonyl,"
   Witherup, S., et al., Cincinnati, OH, Univ. of Ci

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 12 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - chronic pulmonary edema
   Blood - hemorrhage
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 39,1,1987

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 76 mg/m3/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - conjunctive irritation
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 58600 ug/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 20,553,1978

WGK Germany	3
Hazard statements
H300+H330 H311 Toxic in contact with skin 皮肤接触中毒 H351 Suspected of causing cancer 怀疑致癌 H310+H330 H315 Causes skin irritation 会刺激皮肤 H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。 H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官 H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment	Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECS	OP1450000
Precautionary statements
P273 Avoid release to the environment. 避免释放到环境中。 P301+P310 P284 Wear respiratory protection.? 佩戴呼吸保护装置。 P302+P350 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word	Danger
Packing Group	II
UN Number	UN3281
Risk Statements
R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒 R48/23 R26 Very toxic by inhalation 吸入极毒 R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒 R50/53 R38 Irritating to skin 刺激皮肤 R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用 R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）； S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾； S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置； S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书； S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗； S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套； S20 When using do not eat or drink 使用时，不得进食，饮水； S4 Keep away from living quarters 远离生活区； S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Storage condition	Air Sensitive
Hazard Codes	T T+,N

{uni_hamburg} Short: II/2

Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds

Author: König, E.

Editor: Hellwege, K.-H.; Hellwege, A.M.

Source: Landolt-Börnstein, New Series

Volume: II/2

Year: 1966

ISBN: 3-540-03593-1

ISBN: 978-3-540-03593-0

Internet Resource: DOI:10.1007/b19948

RefComment: 170 figs., XII, 578 pages. Hardcover

Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.

{uni_hamburg} Short: III/20b

Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb

Author: Chihara, H.; Nakamura, N.

Editor: Hellwege, K.-H.; Hellwege, A.M.

Source: Landolt-Börnstein, New Series

Volume: III/20b

Year: 1988

Keyword: NQR

ISBN: 3-540-18483-X

ISBN: 978-3-540-18483-6

Internet Resource: DOI:10.1007/b86664

RefComment: IX,717 pages. Hardcover

Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.

{uni_hamburg} Short: III/35E

Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17

Author: Duddeck, H.; Toth, G.; Simon, A.

Editor: Gupta, R.R.; Lechner, M.D.

Source: Landolt-Börnstein, New Series

Volume: III/35E

Year: 2002

Keyword: Alipathic and Aromatic hydrocarbons; Coupling consta

12108-13-3 H17856 (Methylcyclopentadienyl)manganese(I) tricarbonyl
2-甲基环戊二烯三羰基锰

化学属性

Mol. Formula	C9H7MnO3
Mol. Weight	218.09
Refractive index	n20/D 1.584(lit.)
Vapor Density	>;1 (vs air)
Boiling Point	233°C
Vapor Pressure	0.05 mmHg ( 20 °C)
Density	1.38
Melting Point	-2.2°C
Flash Point	205°F
Solubility	Insoluble in water. Soluble in hydrocarbon solvents, alcohols, ether, acetone
TSCA	Yes
Appearance	yellow liq.

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

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(Methylcyclopentadienyl)manganese(I) tricarbonyl 2-甲基环戊二烯三羰基锰

规格: 98%

化学属性

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