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tert-Butyldimethylsilyl Trifluoromethanesulfonate 叔丁基二甲基硅基三氟甲磺酸酯

规格: 97%

CAS: 69739-34-0

产品编号: H98338

MDL: MFCD00000405

品牌: INFI

Chemical Name	tert-Butyldimethylsilyl Trifluoromethanesulfonate
CAS Number	69739-34-0
Synonym	(1,1-Dimethylethyl)dimethylsilyl Trifluoromethanesulfonate TBDMS triflate, Trifluoromethanesulfonic acid tert-butyldimethylsilylester TBDMS 三氟甲磺酸酯三氟甲磺酸叔丁基二甲基硅基酯 Trifluoromethanesulfonic Acid (1,1-Dimethylethyl)dimethylsilyl ester Trifluoromethanesulfonic Acid tert-Butyldimethylsilyl Ester tert-Buty tert-Butyldimethylsilyl triflate 三氟甲烷磺酸叔丁基二甲基甲硅烷酯三氟甲烷磺酸叔丁基二甲基甲硅烷酯，叔丁基二甲硅基三氟甲磺酸酯三氟甲磺酸叔丁基二甲硅烷酯;三氟甲烷磺酸叔丁基二甲基硅烷基酯;叔丁基二甲硅烷基三氟甲磺酸酯;TBDMS 三氟甲磺酸酯;叔丁基二甲基硅基三氟甲磺酸酯叔丁基二甲基硅基三氟甲磺酸酯叔丁基二甲基硅烷基三氟甲烷磺酸酯叔丁基二甲硅基三氟甲磺酸酯
PubChem Substance ID	87577284
EC Number	274-102-0
Beilstein Registry Number	2370068
MDL Number	MFCD00000405
Reaxys-RN	2370068
Chemical Name Translation	叔丁基二甲基硅基三氟甲磺酸酯
LabNetwork Molecule ID	LN00011291
InChIKey	WLLIXJBWWFGEHT-UHFFFAOYSA-N

常用在顺式-双(链烯基)环氧乙烷上引入大位阻的叔丁基二甲基硅基，促进室温 Cope 重排反应生成 2-CF3-4,5-二氢噁庚英；还可与与硫代坊共同用于促进快速高效的硫族化物-Morita-Baylis-Hillman 反应。

{ALF} For general reactions of trialkylsilyl perfluoroalkanesulfonates, see Trimethylsilyl trifluoromethanesulfonate, A12535; reviews: Synthesis, 1 (1982); Adv. Silicon Chem., 1, 189 (1991).

{ALF} Has been used in a sequence for the conversion of N-Boc to N-Cbz: Tetrahedron Lett., 26, 5543 (1985). For an alternative method for this transformation, see Benzyl 2,2,2-trichloroacetimidate, A12387.

{ALF} Treatment of ɑß-unsaturated esters containing a suitably-placed ketone function with the reagent and triethylamine results in tandem intramolecular Michael-aldol reactions to give cyclobutanone derivatives: J. Am. Chem. Soc., 115, 8107 (1993).

{TRC} Hua, D.H. et al.L e-ROS Encyc. Reag. Org. Synth., No pp. given (2001); Suzuki, T. et al.: Synthesis, 4, 555 (2001);

{ALF} Powerful silylating agent (see Appendix 4) and Lewis acid; compare tert-Butyldimethylchlorosilane, A13064 and 3429. Silylation of hindered alcohols can be effected with TBDMS-OTf and 2,6-lutidine, where other reagents are unsuccessful: Tetrahedron Lett., 22, 3455 (1981).

69739-34-0 H98338 tert-Butyldimethylsilyl Trifluoromethanesulfonate
叔丁基二甲基硅基三氟甲磺酸酯

化学属性

Mol. Formula	C7H15F3O3SSi
Mol. Weight	264
Refractive index	1.3840 to 1.3880
Boiling Point	65-67
Density	1.151
Flash Point	36°C(lit.)
TSCA	No
Appearance	无色至淡黄色液体。
Stability	对湿度敏感
pH	:A

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

tert-Butyldimethylsilyl Trifluoromethanesulfonate 叔丁基二甲基硅基三氟甲磺酸酯

规格: 97%

化学属性

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