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Tri(o-tolyl)phosphine 三(邻甲苯基)膦

规格: 98%
CAS: 6163-58-2
产品编号: H97472
MDL: MFCD00008514
品牌: INFI
Chemical NameTri(o-tolyl)phosphine
CAS Number6163-58-2
Alfabeta NameTRITOLYLPHOSPHINE M()-
MDL NumberMFCD00008514
Synonym Tri(2-methylphenyl)phosphine
EC Number228-193-9
Beilstein Registry Number661212
PubChem Substance ID80271
Reaxys-RN661212
Chemical Name Translation三(邻甲苯基)膦
InChIKeyCOIOYMYWGDAQPM-UHFFFAOYSA-N
LabNetwork Molecule IDLN00173237
InChIInChI=1S/C21H21P/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3/h4-15H,1-3H3
Canonical SMILESCC1=C(C=CC=C1)P(C(C=CC=C2)=C2C)C(C=CC=C3)=C3C
IUPAC Nametris(2-methylphenyl)phosphane
  • 配体,用于钌催化的醇的氨基化反应。
  • {ALD} Beilstein: 16,III,835
  • {PUB} Crystallography Open Database (COD)|PubChem --- Bulky triarylarsines are effective ligands for palladium catalysed Heck olefination. --- https://pubmed.ncbi.nlm.nih.gov/15824787
  • {ALF} Preferred phosphine ligand for use in combination with Pd salts in the Heck-type coupling reactions of vinylic halides. For examples, see Palladium(II)­ acetate, 10516. For a review of the Heck reaction, see: Org. React., 27, 345 (1982).
  • {PUB} PubChem --- Palladium-Catalyzed Cross-Coupling of Sterically Demanding Boronic Acids with α-Bromocarbonyl Compounds --- https://pubmed.ncbi.nlm.nih.gov/21863787
  • {PUB} PubChem --- Palladium-Catalyzed Intramolecular Coupling between Aryl Iodides and Allyl Moieties via Thermal and Microwave-Assisted Conditions --- https://pubmed.ncbi.nlm.nih.gov/15631454
  • {PUB} PubChem --- Palladium‐Catalyzed Intramolecular C(sp3)H Functionalization: Catalyst Development and Synthetic Applications --- https://pubmed.ncbi.nlm.nih.gov/17044108
  • {PUB} PubChem --- Remarkable effect of phosphine on the reactivity of O,P-acetal--efficient substitution reaction of O,P-acetal --- https://pubmed.ncbi.nlm.nih.gov/20449525
  • {PUB} PubChem --- Synthesis of InP nanofibers from tri(m-tolyl)phosphine: an alternative route to metal phosphide nanostructures --- https://pubmed.ncbi.nlm.nih.gov/20023954
  • {PUB} PubChem|Springer Nature --- A concise synthetic pathway for trans-metanicotine analogues --- https://pubmed.ncbi.nlm.nih.gov/10896048
  • {PUB} PubChem|Springer Nature --- A direct method for the synthesis of orthogonally protected furyl- and thienyl- amino acids --- https://pubmed.ncbi.nlm.nih.gov/25583604
  • {PUB} PubChem|Springer Nature --- Stereoselective synthesis of (+/-)-epibatidine analog:(+/-)-2beta-(2-chloro-5-pyridinyl)-8-azabicyclo[3.2.1] octane --- https://pubmed.ncbi.nlm.nih.gov/10403134
  • {PUB} PubChem|Springer Nature --- Synthesis and evaluation of vesamicol analog (-)-o-[11C]methylvesamicol as a PET ligand for vesicular ace
  • 6163-58-2 H97472 Tri(o-tolyl)phosphine
三(邻甲苯基)膦

    化学属性

    Mol. FormulaC21H21P
    Mol. Weight304.37
    Density1.589
    Melting Point123-125°C
    TSCAYes
    Boiling Point412.4±44.0 °C at 760 mmHg
    Appearance white xtl.
    Stabilityair sensitive

    *以上化合物性质及应用等信息仅供参考