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Palladium(II) chloride 氯化钯(II)

规格: 99%, pd>59.5%
CAS: 7647-10-1
产品编号: H78811
MDL: MFCD00003558
品牌: INFI
Chemical NamePalladium(II) Chloride
CAS Number7647-10-1
Alfabeta NamePALLADIUMCHLORIDE II()
MDL NumberMFCD00003558
PubChem Substance ID24290
EC Number231-596-2
Merck Number6990
Synonym Palladium(II) chloride
Beilstein Registry Number2384789
Chemical Name Translation氯化钯(易涉毒)
Wiswesser Line NotationPD G2
LabNetwork Molecule IDLN00170222
InChIInChI=1S/2ClH.Pd/h2*1H;/q;;+2/p-2
Canonical SMILESCl[Pd]Cl
IUPAC Namedichloropalladium
  • 1、点滴测定钯、汞、铊和碘,提纯稀有气味,氯化钯试纸检验一氧化碳、检定钴。
  • 2、催化剂,末端烯径(α-烯径)生成甲基酮的氧化催化。
  • 3、通过Wacker反应,在水溶液中用空气作氧化剂,使烯径氧化成醛。
  • 4、用于合成半导体含金属聚合体,该聚合体具有聚吡咯骨架,符合能量最小且接近平面。
  • {ALFA} For use in the microwave accelerated Heck coupling reaction of aryl halides in the ionic liquid 1-n-Butyl-3-methyl­imidazolium hexafluorophosphate, L19086, see: J. Org. Chem., 67, 6243 (2002).
  • {PUB} Hazardous Substances Data Bank (HSDB)|PubChem --- Further studies on the ability of different metal salts to influence the DNA synthesis of human lymphoid cells --- https://pubmed.ncbi.nlm.nih.gov/3941015
  • {ALFA} In combination with benzoquinone as reoxidant, N-methylarylamines add to Michael acceptors to give enamines: J. Org. Chem., 46, 2561 (1981).
  • {ALFA} In the presence of triphenylphosphine and MeLi, a Pd(0) species is generated which catalyzes the coupling of organolithium reagents with aryl or vinyl halides. For tabulated results, see: Org. Synth. Coll., 7, 172 (1990):
  • {ALD} Merck: 14,6990
  • {SA} Miki, K.; Nishino, F. et al. J. Am. Chem. Soc. 124 , 5260, (2004)
  • {PUB} PubChe
  • {PUB} PubChem --- Application of high-performance thin-layer chromatography for the detection of organophosphorus insecticides in human serum after acute poisoning --- https://pubmed.ncbi.nlm.nih.gov/9518173
  • {PUB} PubChem --- Oxygen-promoted PdCl2-catalyzed ligand-free Suzuki reaction in aqueous media --- https://pubmed.ncbi.nlm.nih.gov/21152641
  • {PUB} PubChem --- Palladium-Catalyzed Tandem Dimerization and Cyclization of Acetylenic Ketones: A Convenient Method for 3,3‘-Bifurans Using PdCl2(PPh3)2 --- https://pubmed.ncbi.nlm.nih.gov/11529726
  • {PUB} PubChem --- Patch test–relevant concentrations of metal salts cause localized cytotoxicity, including apoptosis, in skin ex vivo --- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9291529
  • {PUB} PubChem --- Release of prostaglandin E2, IL‐6 and IL‐8 from human oral epithelial culturemodels after exposure to compounds of dental materials --- https://pubmed.ncbi.nlm.nih.gov/11037761
  • {PUB} PubChem --- Spectrophotometric complexation of cephalosporins with palladium (II) chloride in aqueous and non-aqueous solvents --- https://pubmed.nc
  • 7647-10-1 H78811 Palladium(II) chloride
氯化钯(II)

    化学属性

    Mol. FormulaCl2Pd
    Mol. Weight177.33
    Density3.98
    Melting Point678 - 680 °C (lit.)
    TSCAYes
    SolubilitySoluble in dilute mineral acids, aqueous metal halides
    Appearance rust colored xtl.
    Stability易吸潮

    *以上化合物性质及应用等信息仅供参考