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(S)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole (S)-5,5'-双(二苯基膦)-4,4'-二-1,3-苯并二茂

规格: 99%

CAS: 210169-54-3

产品编号: H76058

MDL: MFCD09753005

品牌: INFI

Chemical Name	(S)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole
Synonym	(R)-(+)-5,5′-双(二苯基膦)-4,4′-二-1,3-苯并二噁茂 [4(R)-(4,4′-二-1,3-苯并二噁茂)-5,5′-二基]双[二苯基膦] (S)-(-)-5,5′-双(二苯基膦)-4,4′-二-1,3-苯并二噁茂 (S)-SEGPHOS®
MDL Number	MFCD09753005
CAS Number	210169-54-3
Chemical Name Translation	(S)-5,5'-双(二苯基膦)-4,4'-二-1,3-苯并二茂
Reaxys-RN	11841467
PubChem Substance ID	329761551

WGK Germany	3

{SA} Gao, X.; et al., Enhanced anti-Diastereo- and Enantioselectivity in Alcohol-Mediated Carbonyl Crotylation Using an Isolable Single Component Iridium Catalyst J. Org. Chem. 76 , 2350-2354, (2011)

{SA} Guo, X.-X.; et al., Rhodium-catalyzed enantioselective alkynylative cyclization of allenyl aldehydes with terminal alkynes Tetrahedron Asymmetry 21 , 1730-1736, (2010)

{SA} Maeda, T.; et al., Diastereo- and Enantioselective Hydrogenation of α-Amino-β-Keto Ester Hydrochlorides Catalyzed by an Iridium Complex with MeO-BIPHEP and NaBArF: catalytic Cycle and Five-Membered Chelation Mechanism of Asymmetric Hydrogenation Chem. Eur. J. 16 , 11954-11962, (2010)

{SA} Miura, T.; et al., Nickel-Catalyzed Denitrogenative Annulation Reactions of 1,2,3-Benzotriazin-4(3H)-ones with 1,3-Dienes and Alkenes J. Org. Chem. 75 , 5359-5362, (2010)

{SA} Ogaki, S.; et al., Enantioselective Synthesis of Axially Chiral Hydroxy Carboxylic Acid Derivatives by Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition J. Org. Chem. 76 , 1926-1929, (2011)

{SA} Suda, T.; et al., Rhodium-Catalyzed Asymmetric Formal Olefination or Cycloaddition: 1,3-Dicarbonyl Compounds Reacting with 1,6-Diynes or 1,6-Enynes Angew. Chem. Int. Ed. Engl. 50 , 4475-4479, (2011)

210169-54-3 H76058 (S)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole
(S)-5,5'-双(二苯基膦)-4,4'-二-1,3-苯并二茂

化学属性

Mol. Formula	C38H28O4P2
Mol. Weight	611
Melting Point	168-172°C
Appearance	off-white pwdr.
Density	1.0

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

(S)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole (S)-5,5'-双(二苯基膦)-4,4'-二-1,3-苯并二茂

规格: 99%

化学属性

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