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Bis(cyclopentadienyl)zirconium chloride hydride 氢氯二茂锆

规格: 95%

CAS: 37342-97-5

产品编号: H63619

MDL: MFCD02089401

品牌: INFI

Chemical Name	Bis(Cyclopentadienyl)Zirconium Chloride Hydride
Synonym	Bis(cyclopentadienyl)chlorohydrozirconium
MDL Number	MFCD02089401
PubChem Substance ID	87577928
EC Number	253-479-5
CAS Number	37342-97-5
Merck Number	8396
Chemical Name Translation	氢氯二茂锆
InChIKey	UVWUHPCWBZSERX-UHFFFAOYSA-M
Canonical SMILES	[][Zr]([H])(Cl)[].c1cccc1.c2cccc2

转化氨基化合物生成醛类化合物；石蜡和炔烃的功能化试剂。

{ALF} Reagent for selective reduction of secondary carboxamides to imines, a transformation otherwise difficult to achieve since imines are normally more easily reduced than amides: J. Org. Chem., 61, 4115 (1996); tertiary amides can also be reduced to aldehydes at room temperature: J. Am. Chem. Soc., 122, 11995 (2000). Reduction of phosphine oxides and phosphine sulfides to phosphines under mild conditions has also been reported: Tetrahedron Lett., 38, 5997 (1997).

{ALF} Catalyzes the hydroboration of alkynes with Pinacolborane, L17558, to form alkenylboronates with high regio- and stereoselectivity: Organometallics, 14, 3127 (1995). Alkenes are similarly converted to alkylboronates: J. Am. Chem. Soc., 118, 909 (1996).

{ALF} Reaction with alkenes (hydrozirconation) results in zirconocene alkyl chlorides: Tetrahedron Lett., 28, 3895 (1987). Useful products are obtained by reaction of these with various electrophiles. With O-(mesitylsulfonyl)hydroxylamine, primary amines are obtained, with generally good yields and regioselectivity: J. Org. Chem., 60, 1912 (1995).

{ALF} For a brief feature on the reagent, see: Synlett, 1179 (1999); review of synthetic applications of organozirconocene compounds: Tetrahedron, 52, 12853 (1996)

{ALD} Merck: 14,8396

37342-97-5 H63619 Bis(cyclopentadienyl)zirconium chloride hydride
氢氯二茂锆

化学属性

Mol. Formula	C10H11ClZr
Mol. Weight	257.87
Melting Point	300°C
TSCA	No
Stability	对光、空气和湿度敏感
Appearance	off-white pwdr.
Boiling Point	41.5°C at 760 mmHg
Danger-Level	-
pH	-:-
Redox	-
Density	1.0

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Bis(cyclopentadienyl)zirconium chloride hydride 氢氯二茂锆

规格: 95%

化学属性

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