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Di-tert-butylphosphine 二叔丁基膦

规格: 0.5M (10 wt.%) solution in hexanes, SpcSeal
CAS: 819-19-2
产品编号: H62479
MDL: MFCD00134241
品牌: INFI
Chemical NameDi-tert-butylphosphine
Synonym {uni_hamburg} Di-tert-butylphosphine Di-t-butylphosphine Phosphine, bis(1,1-dimethylethyl)- 二叔丁基膦 Di-tertbutylphosphine Di-tert-butyl-phosphane
CAS Number819-19-2
EC Number250-023-7
Beilstein Registry Number1918492
MDL NumberMFCD00134241
PubChem Substance ID136643
Chemical Name Translation二-叔丁基膦
InChIKeyCRHWEIDCXNDTMO-UHFFFAOYSA-N
LabNetwork Molecule IDLN00010339
InChIInChI=1S/C8H19P/c1-7(2,3)9-8(4,5)6/h9H,1-6H3
IUPAC Nameditert-butylphosphane
  • {PUB} Crystallography Open Database (COD)|PubChem --- Air stable, sterically hindered ferrocenyl dialkylphosphines for palladium-catalyzed C[bond]C, C[bond]N, and C[bond]O bond-forming cross-couplings --- https://pubmed.ncbi.nlm.nih.gov/12153253
  • {PUB} Crystallography Open Database (COD)|PubChem|The Cambridge Structural Database --- Bulky N-Substituted 1,3-Benzazaphospholes: Access via Pd-Catalyzed C−N and C−P Cross Coupling, Lithiation, and Conversion to Novel P═C−PtBu2 Hybrid Ligands --- https://pubmed.ncbi.nlm.nih.gov/18610971
  • {PUB} PubChem --- Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides --- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2819174
  • {PUB} PubChem --- Palladium-Catalyzed α-Arylation of Esters --- https://pubmed.ncbi.nlm.nih.gov/11506555
  • {uni_hamburg} Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
  • {PUB} Springer
  • {PUB} Springer Nature --- Absence of Pπ-conjugation in vinylogs of cyano- and acylphosphines --- https://doi.org/10.1007/bf00851307
  • 819-19-2 H62479 Di-tert-butylphosphine
二叔丁基膦

    化学属性

    Mol. FormulaC8H19P
    Mol. Weight146.22
    Density0.77
    Flash Point−1 °F
    Boiling Point-17°C
    Appearance colorless liq.
    Melting Point-17°C
    Stabilityair sensitive

    *以上化合物性质及应用等信息仅供参考