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1,3-Bis(diphenylphosphino)propane 1,3-双(二苯膦基)丙烷

规格: 95%
CAS: 6737-42-4
产品编号: H60908
MDL: MFCD00003050
品牌: INFI
Chemical Name1,3-Bis(diphenylphosphino)propane
CAS Number6737-42-4
Alfabeta NameBISDIPHENYLPHOSPHINOPROPANE 13()-,
MDL NumberMFCD00003050
EC Number229-791-2
Beilstein Registry Number2821785
Synonym 1,3-Bis(diphenylphosphino)propane
PubChem Substance ID81219
Reaxys-RN2821785
Chemical Name Translation1,3-双(二苯基膦)丙烷
LabNetwork Molecule IDLN00155114
InChIInChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
Canonical SMILESC=1C=CC(=CC1)P(C=2C=CC=CC2)CCCP(C=3C=CC=CC3)C=4C=CC=CC4
IUPAC Name3-diphenylphosphanylpropyl(diphenyl)phosphane
  • {ALF} Chelating phosphorus ligand which forms a 1:1 complex with NiCl2, which is an efficient catalyst for the coupling of Grignard reagents with aryl, vinylic or heterocyclic halides: Bull. Chem. Soc. Jpn., 49, 1958 (1976); Tetrahedron, 38, 3347 (1982); Synthesis, 386 (1988).
  • {PUB} Crystallography Open Database (COD)|PubChem --- Aromatic C–F activation by complexes containing the {Pt2S2} core via nucleophilic substitution: a combined experimental and theoretical study --- https://pubmed.ncbi.nlm.nih.gov/19623398
  • {PUB} Crystallography Open Database (COD)|PubChem --- Bis[1,3-bis-(diphenyl-phosphan-yl)propane]-copper(I) tetra-chlorido-gallate(III) --- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393151
  • {PUB} Crystallography Open Database (COD)|PubChem --- Gold(I) Macrocycles and Topologically Chiral [2]Catenanes --- https://pubmed.ncbi.nlm.nih.gov/11942834
  • {PUB} Crystallography Open Database (COD)|PubChem --- Self-Assembly of Flexible Supramolecular Metallacyclic Ensembles: Structures and Adsorption Properties of Their Nanoporous Crystalline Frameworks --- https://pubmed.ncbi.nlm.nih.gov/15327323
  • {PUB} Crystallography Open Database (COD)|PubChem|Springer Nature --- Dynamics of ion-regulated photoinduced electron transfer in BODIPY-BAPTA conjugates --- https://pubmed.ncbi.nlm.nih.gov/23243669
  • {PUB} Crystallography Open Database (COD)|PubChem|The Cambridge Structural Database --- Diphosphine-catalyzed mixed double-Michael reaction: a unified synthesis of indolines, dihydropyrrolopyridines, benzimidazolines, tetrahydroquinolines, tetrahydroisoquinolines, dihydrobenzo-1,4-oxazines, and dihydrobenzo-3,1-oxazines. --- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2835628
  • {PUB} PubChem --- A General Palladium‐Catalyzed Carbonylative Synthesis of Chromenones from Salicylic Aldehydes and Benzyl Chlorides --- https://pubmed.ncbi.nlm.nih.gov/23939874
  • {PUB} PubChem --- A Novel Palladium-Catalyzed Synthesis of 1,2-Dihydroquinoxalines and 3,4-Dihydroquinoxalinones --- https
  • 6737-42-4 H60908 1,3-Bis(diphenylphosphino)propane	1,3-双(二苯膦基)丙烷

    化学属性

    Mol. FormulaC27H26P2
    Mol. Weight412.45
    Density1.422
    Melting Point63-65°C
    TSCAYes
    Solubility不溶
    Flash Point235°C
    Appearance white xtl.
    Boiling Point529.7°C at 760 mmHg
    RedoxReduction

    *以上化合物性质及应用等信息仅供参考