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Triisopropylchlorosilane 三异丙基氯硅烷

规格: 97%
CAS: 13154-24-0
产品编号: H59263
MDL: MFCD00009656
品牌: INFI
Chemical NameTriisopropylsilyl chloride
MDL NumberMFCD00009656
Synonym Chlorotriisopropylsilane, 97+% Chlorotriisopropylsilane, Triisopropylsilyl chloride TIPSCI TIPSCl TRIISOPROPYLSILYL CHLORIDE Triisopropylsilyl chloride Chlorotriisopropylsilane 三异丙基氯甲硅烷
CAS Number13154-24-0
Beilstein Registry Number1737446
PubChem Substance ID87576875
EC Number250-023-7
Alfabeta NameTRIISOPROPYLSILYLCHLORIDE
Reaxys-RN1737446
Chemical Name Translation三异丙基氯硅烷
InChIKeyKQIADDMXRMTWHZ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00007870
  • {ALF} For a comprehensive review of the TIPS group in organic chemistry, see: Chem. Rev., 95, 1009 (1995). See also Triisopropyl­silyl­ trifluoromethanesulfonate, B21127.
  • {ALF} Cleavage is usually accomplished by treatment with F-: J. Org. Chem., 51, 4941 (1986); see Tetra-n-butyl­ammonium fluoride, A10588. Alternative methods include dilute HCl: Tetrahedron Lett., 2865 (1974), or 80% AcOH: J. Carbohydr., Nucleosides, Nucleotides, 3, 197 (1976).
  • {ALF} Reagent for the protection of alcohols as triisopropylsilyl (TIPS) ethers. See Appendix 4. Methods of introduction include imidazole in DMF: Tetrahedron Lett., 2865 (1974), or imidazole/DMAP: Chem. Lett., 41 (1987). Also useful for N-protection. The steric bulk of TIPS makes it useful as a regio- and stereodirecting group, allowing selective protection of primary hydroxyl in the presence of secondary: Tetrahedron Lett., 2865 (1974). TIPS ethers are more resistant to acidic hydrolysis than TBDMS ethers, but less so than tert-butyldiphenylsilyl (TBDPS) ethers. However, they are more resistant to basic hydrolysis than either TBDMS or TBDPS derivatives: J. Org. Chem., 45, 4797 (1980); 49, 3239 (1984); Tetrahedron Lett., 24, 3455 (1983).
    • 13154-24-0 H59263 Triisopropylchlorosilane 三异丙基氯硅烷

    化学属性

    Mol. FormulaC9H21ClSi
    Mol. Weight193
    Density0.901
    Refractive index1.4520 to 1.4540
    Flash Point62°C(lit.)
    TSCANo
    Boiling Point198
    Vapor Pressure1.16 mmHg ( 20 °C)
    pH:A

    *以上化合物性质及应用等信息仅供参考

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