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Bis(acetonitrile)dichloropalladium(II) 双(乙腈)二氯化钯(II)

规格: 99%，Pd>41%

CAS: 14592-56-4

产品编号: H50073

MDL: MFCD00013122

品牌: INFI

Chemical Name	Bis(acetonitrile)dichloropalladium(II)
Synonym	bis(acetonitrile)dichloropalladium TRANS-DICHLOROBIS(ACETONITRILE)PALLADIUM BIS(ACETONITRILE)PALLADIUM(II) DICHLORIDE 反式双(乙腈)氯化钯(II) 氯化钯(II)二乙腈络合物双乙腈氯化钯 DICHLOROBIS(ACETONITRILE)PALLADIUM(III) Palladium, bis(acetonitrile)dichloro- BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE TRANS-BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE 双(乙腈)二氯钯(II), PD 40.5% PALLADIUM DICHLOROBIS(ACETONITRILE) bis (acetontrile) dichloropalladium (II) DICHLOROBIS(ACETONITRILE)PALLADIUM(II) Dichlorobis(acetoni Bis(acetonitrile)dichloropalladium(II) 二乙腈基二氯化钯双(乙腈)二氯钯(II) {Chemica Dichlorobis(acetonitrile)palladium(II) BIS(ACETONITRILE)DICHLOROPALLADIUM(II)
MDL Number	MFCD00013122
PubChem Substance ID	84541
EC Number	238-637-3
CAS Number	14592-56-4
Beilstein Registry Number	14640205
Reaxys-RN	14640205
Chemical Name Translation	双(乙腈)氯化钯(II)
InChIKey	RBYGDVHOECIAFC-UHFFFAOYSA-L
InChI	InChI=1S/2C2H3N.2ClH.Pd/c21-2-3;;;/h21H3;2*1H;/q;;;;+2/p-2
LabNetwork Molecule ID	LN00188715

{ALF} A 6:1 molar ratio of the high-temperature phase-transfer catalyst Tetraphenylphosphonium chloride, A10575, and the Pd complex, provides an effective catalyst for the Heck reaction of normally unreactive aryl halides, e.g. chlorobenzene with styrene to give stilbene. The reaction is performed at 140-150o in DMF or NMP in the presence of sodium acetate: Angew. Chem. Int. Ed., 37, 481 (1997).

{ALF} Catalyses the cleavage of phenolic TBDMS ethers under mild conditions: Tetrahedron Lett., 37, 153 (1996), and, in the presence of 2-Bromomesitylene, A12277, promotes one-pot desilylation-oxidation of aliphatic silyl ethers to aldehydes or ketones: J. Org. Chem., 61, 2918 (1996); cf J. Org. Chem., 48, 1286 (1983).

{ALF} Effective alternative catalyst to trans-Dichlorobis(triphenylphosphine)palladium(II), 10491, for the carbonylative cross-coupling of arylboronic acids with aryl iodides to give unsymmetrical benzophenones: Tetrahedron Lett., 34, 7595 (1993); see also Appendix 5.

{ALF} Organic-soluble complex for catalysis of a variety of reactions, with the advantage over trans-Bis(benzonitrile)dichloropalladium(II), 10006, that the nitrile by-product, being volatile and water-miscible, is readily removed in the workup. In the presence of triethylamine, ortho-allylanilines undergo cyclization to indoles: J. Am. Chem. Soc., 98, 2674 (1976):

14592-56-4 H50073 Bis(acetonitrile)dichloropalladium(II) 双(乙腈)二氯化钯(II)

化学属性

Mol. Formula	PdCl2
Mol. Weight	259
Solubility	Soluble in acetonitrile, acetone, chloroform
TSCA	No
Density	1.422
Melting Point	300 ºC
Appearance	orange pwdr.

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Bis(acetonitrile)dichloropalladium(II) 双(乙腈)二氯化钯(II)

规格: 99%，Pd>41%

化学属性

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