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Dichloro(p-cymene)ruthenium(II) dimer 二氯双(4-甲基异丙基苯基)钌(II)

规格: 98%
CAS: 52462-29-0
产品编号: H48910
MDL: MFCD00064793
品牌: INFI
Chemical NameDichloro(p-cymene)ruthenium(II) dimer
MDL NumberMFCD00064793
Synonym Dichloro(p-cymene)ruthenium(II) dimer
EC Number435-530-5
CAS Number52462-29-0
PubChem Substance ID87569153
Beilstein Registry Number2384789
Chemical Name Translation二氯(4-甲基异丙苯)钌(II)二聚体
LabNetwork Molecule IDLN00155202
Canonical SMILESCC(C)C1=CC=C(C)C=C1.CC(C)C2=CC=C(C)C=C2.C[Ru](Cl[Ru]3(Cl)C)(Cl3)Cl
  • Hydrosilylation Catalysts
  • Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
  • Cyclometalated ruthenium complexes with arylimines and nitrogen-containing heterocycles via C-H bond activation
  • {ALF} Catalyst for highly stereoselective hydrosilylation of terminal alkynes: Org. Lett., 2, 1887 (2000). Also promotes the aerobic oxidation of benzylic and allylic alcohols to the corresponding aldehydes: Tetrahedron Lett., 41, 7507 (2000).
  • {ALF} In the presence of pyrrolidine, catalyzes the 1,4-addition of terminal alkynes to enones to give δ-ynones: Org. Lett., 3, 2089 (2001).
  • {ALF} Effective catalyst for dehydration of aldoximes to nitriles: Org. Lett., 3, 4271 (2001).
  • {ALF} Verstaile catayst for C-C bond formation by C-H bond activation, for example in the coupling of vinylsilanes with aromatic C-H bonds to give arylethyl silanes: Angew. Chem. Int. Ed., 45, 8232 (2006).
  • 52462-29-0 H48910 Dichloro(p-cymene)ruthenium(II) dimer
二氯双(4-甲基异丙基苯基)钌(II)

    化学属性

    Mol. FormulaC20H28Cl4Ru2
    Mol. Weight612.38
    TSCANo
    Melting Point247.0-250.0°C
    Density1.422
    Stability对光敏感

    *以上化合物性质及应用等信息仅供参考