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Copper(I) bromide 溴化亚铜

规格: 98.5%

CAS: 7787-70-4

产品编号: H48354

MDL: MFCD00010969

品牌: INFI

Chemical Name	Copper(I) bromide
Synonym	Copper(I) bromide
MDL Number	MFCD00010969
PubChem Substance ID	24593
CAS Number	7787-70-4
EC Number	232-131-6
Beilstein Registry Number	2384789
Merck Number	14,2659
Chemical Name Translation	溴化亚铜
LabNetwork Molecule ID	LN00194961
InChI	InChI=1S/BrH.Cu/h1H;/q;+1/p-1
Canonical SMILES	[Cu]Br

有机反应催化剂。

{ALFA} Reaction of Grignard reagents with aromatic nitriles is potentially a useful route to ketones via the imine. However, in the absence of a catalyst, reaction is generally very slow and gives indifferent yields. In the presence of CuBr, tert-butylmagnesium chloride reacts readily with benzonitrile to give tert-butyl phenyl ketone in 94% yield: J. Org. Chem., 52, 3901 (1987).

{ALFA} Precursor of organocopper reagents. For reviews, see: Org. React., 22, 253 (1975); 41, 135 (1992); Synthesis, 63 (1972); Tetrahedron, 45, 349 (1989).

{ALFA} Catalyst for 1,4-addition of Grignard reagents to enones: J. Org. Chem., 27, 707 (1962); Org. Synth. Coll., 8, 522 (1993).

{ALD} Merck: 14,2659

{uni_hamburg} Short: II/24A

化学属性

Mol. Formula	BrCu
Mol. Weight	143.45
Density	4.69
Melting Point	501 - 507 °C(lit.)
Solubility	Slightly soluble in cold water. Decomposes in hot water. Soluble in HBr, HCl, NH4OH
TSCA	Yes
Boiling Point	1345 °C
Refractive index	2.116
Stability	对光和空气敏感，充氩操作和储存
Flash Point	1345°C
Appearance	off-white to pale-green pwdr.

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Copper(I) bromide 溴化亚铜

规格: 98.5%

化学属性

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