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Dimethyl (2-Oxopropyl)phosphonate 丙酮基膦酸二甲酯

规格: 95%
CAS: 4202-14-6
产品编号: H46956
MDL: MFCD00008769
品牌: INFI
Chemical NameDimethyl acetylmethylphosphonate
CAS Number4202-14-6
EC Number224-110-5
Beilstein Registry Number1766218
MDL NumberMFCD00008769
Synonym Dimethyl acetonylphosphonate
PubChem Substance ID77872
Chemical Name Translation2-氧代丙基膦酸二甲酯
Reaxys-RN1766218
InChIKeyUOWIYNWMROWVDG-UHFFFAOYSA-N
LabNetwork Molecule IDLN00009226
InChIInChI=1S/C5H11O4P/c1-5(6)4-10(7,8-2)9-3/h4H2,1-3H3
Canonical SMILESCC(CP(OC)(OC)=O)=O
IUPAC Name1-dimethoxyphosphorylpropan-2-one
  • {ALD} Beilstein: 4,IV,3604
  • {ALF} For use of ß-ketophosphonates in an annulation sequence for building a cyclohexadienone ring onto a cyclic ketone, see: Synthesis, 855 (1982):
  • {ALF} Horner-Wadsworth-Emmons precursor of ɑß-unsaturated ketones.
  • {PUB} PubChem --- Target-Directed Organocatalysis: A Direct Asymmetric Catalytic Approach to Chiral Propargylic and Allylic Fluorides --- https://pubmed.ncbi.nlm.nih.gov/19419172
  • {PUB} PubChem|Springer Nature --- Ethynylglycine synthon from Garner’s aldehyde: a useful precursor for the synthesis of non-natural amino acids --- https://pubmed.ncbi.nlm.nih.gov/15812682
  • {PUB} PubChem|Springer Nature --- Facile synthesis of hydroxy wilfordic acid, a esterifying unit of anti-HIV sesquiterpene pyridine alkaloids --- https://pubmed.ncbi.nlm.nih.gov/20162393
  • {PUB} PubChem|Springer Nature --- Recent Progress in the Diverse Synthetic Approaches to Phytosphingosine --- https://pubmed.ncbi.nlm.nih.gov/40886224
  • {PUB} Springer Natu
  • {PUB} Springer Nature --- (E) Enol ethers from the stereoselective reduction of α-alkoxy-β-ketophosphonates and Wittig type reaction --- https://doi.org/10.1007/s11426-010-4057-1
  • {PUB} Springer Nature --- 2,4-Disubstituted 4-(1,3-thiazol-5-yl)but-3-en-2-ones: synthetic approaches to and consequent chemical modification --- https://doi.org/10.1007/s00706-020-02612-7
  • {PUB} Springer Nature --- Approaches to Epothilone Carboanalogs Starting from Δ3-Carene --- https://doi.org/10.1023/a:1023442612661
  • {PUB} Springer Nature --- Dialkyl (2-oxopropyl)phosphonates in the synthesis of phosphorylated heterocycles --- https://doi.org/10.1007/s10593-020-02786-2
  • {PUB} Springer Nature --- Efficient synthesis of α,β-unsaturated ketones with trans-selective Horner–Wadsworth–Emmons reaction in water --- https://doi.org/10.1007/s10311-016-0552-8
  • {PUB} Springer Nature --- Galiellalactone: a review on synthetic strategies and tactics --- https://doi.org/10.1007/s11696-022-02630-1
  • {PUB} Springer Nature --- Manganes
  • 4202-14-6 H46956 Dimethyl (2-Oxopropyl)phosphonate
丙酮基膦酸二甲酯

    化学属性

    Mol. FormulaC5H11O4P
    Mol. Weight166.11
    Density1.202
    Boiling Point227°C at 760 mmHg
    Refractive index1.4380 to 1.4410
    Flash Point93.4°C
    TSCANo

    *以上化合物性质及应用等信息仅供参考