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Zirconium tetrachloride 四氯化锆

规格: 99.9%(99.9%-Zr)
CAS: 10026-11-6
产品编号: H46666
MDL: MFCD00011306
品牌: INFI
Chemical NameZirconium(IV) Chloride
Synonym 四氯化锆 Zirconium chloride (ZrCl4), (T-4)- Zirkoniumtetrachlorid Zirconium(IV) chloride Zirconium chloride zirconium (IV) chloride Zirconium tetrachloride Zirconium chloride (Zr2Cl8) Tetrachlorozirconium 四氯化锆 Zirkon(IV)-chlorid, wasserfrei 氯化锆(IV) Zirkon(IV)-chlorid wasserfrei Zirkontetrachlorid ZrCl4 Tetrachlorozirconium Zirconium(IV) chloride, anhydrous 氯化锆
CAS Number10026-11-6
PubChem Substance ID24852962
EC Number233-058-2
MDL NumberMFCD00011306
Merck Number14,10174
Beilstein Registry Number2384789
Chemical Name Translation氯化锆(IV)
LabNetwork Molecule IDLN00198098
  • 用于制金属锆、颜料、纺织品防水剂、皮革鞣剂和分析试剂等。
  • {ALF} For a brief feature on uses of this reagent in synthesis, see: Synlett, 1073 (2003).
  • {ALF} Catalyzes the trans-hydrostannylation of acetylenes with Tri-n-butyl­tin hydride, A13298: J. Chem. Soc., Chem. Commun., 2405 (1995); J. Org. Chem., 61, 4568 (1996). Allylstannanes also add trans-selectively to acetylenes under similar conditions: J. Chem. Soc., Chem. Commun., 1513 (1996).
  • {ALF} Highly efficient and reusable catalyst for acetylation of phenols, thiols, amines and alcohols under solvent-free conditions, claimed to be superior to metal triflates: Synlett, 627 (2004).
  • {uni_hamburg} Short: II/25A
  • {ALF} Lewis acid. Promotes the rearrangement of hydroxy sulfones to ketones: J. Chem. Soc., Chem. Commun., 2289 (1994).
  • {ALF} Superior catalyst for the Fries rearrangement of aryl acetates, giving the least hindered ortho-acetyl phenol in high yields at ambient temperatures: Tetrahedron Lett., 37, 7659 (1996).
  • {ALD} Merck:14,10174
  • {ALF} In the presence of ZrCl4, chloromethyl ethers are formed under mild conditions from acid chlorides and trioxane or paraformaldehyde: Tetrahedron Lett., 43, 6317 (2002).
  • 10026-11-6 H46666 Zirconium tetrachloride
四氯化锆

    化学属性

    Mol. FormulaZrCl4
    Mol. Weight233.04
    Density2.8
    TSCAYes
    Melting Point434 - 440 °C
    Solubility溶于冷水、乙醇、乙醚,不溶于苯、四氯化碳、二硫化碳。
    Vapor Pressure1 mmHg ( 190 °C)
    Stability对湿度敏感
    Boiling Point331°C

    *以上化合物性质及应用等信息仅供参考