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Tris(dimethylamino)phosphine 三(二甲胺基)膦

规格: 99%

CAS: 1608-26-0

产品编号: H42476

MDL: MFCD00008301

品牌: INFI

Chemical Name	Hexamethylphosphorous Triamide
CAS Number	1608-26-0
Synonym	N,N,N',N',N'',N''-Hexamethylphosphinetriamine
MDL Number	MFCD00008301
EC Number	216-534-4
Beilstein Registry Number	4(4)274
PubChem Substance ID	87577088
Reaxys-RN	906778
Chemical Name Translation	三(二甲胺基)膦
LabNetwork Molecule ID	LN00226609
InChI	InChI=1S/C6H18N3P/c1-7(2)10(8(3)4)9(5)6/h1-6H3
Canonical SMILES	CN(C)P(N(C)C)N(C)C
IUPAC Name	N-[bis(dimethylamino)phosphanyl]-N-methylmethanamine

Reagent combination with CCl4 for the conversion of hydroxyl groups to the corresponding chlorides; hydroxyl group activation; dehydrations.

{PUB} Crystallography Open Database (COD)|PubChem --- Phosphorus-Based p-tert-Butylcalix[5]arene Ligands --- https://pubmed.ncbi.nlm.nih.gov/15106987

{PUB} Crystallography Open Database (COD)|PubChem --- Synthesis and Characterization of the Trihalophosphine Compounds of Ruthenium [RuX2(η6-cymene)(PY3)] (X = Cl, Br, Y = F, Cl, Br) and the Related PF2(NMe2) and P(NMe2)3Compounds; Multinuclear NMR Spectroscopy and the X-ray Single Crystal Structures of [RuBr2(η6-cymene)(PF3)], [RuBr2(η6-cymene)(PF2{NMe2})], and [RuI2(η6-cymene)(P{NMe2}3)] --- https://pubmed.ncbi.nlm.nih.gov/18808107

{PUB} Crystallography Open Database (COD)|PubChem|The Cambridge Structural Database --- Synthesis of Transient and Stable C-Amino Phosphorus Ylides and Their Fragmentation into Transient and Stable Carbenes --- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2440685

{ALF} Has also been used for a variety of other reductions including that of ozonolysis intermediates: Helv. Chim. Acta, 50, 2387 (1967), and of primary alkyl nitro compounds to nitriles: Synthesis, 36 (1979). Bromohydrins can be converted to alkenes, by reductive elimination from their triflate esters: J. Am. Chem. Soc., 102, 1433 (1980):

{PUB} Human Metabolome Database (HMDB)|PubChem|Springer Nature --- Consumption and Metabolism of 1,2-Dimethoxy-4-(3-Fluoro-2-Propenyl)Benzene, a Fluorine Analog of Methyl Eugenol, in the Oriental Fruit Fly Bactrocera dorsalis (Hendel) --- https://pubmed.ncbi.nlm.nih.gov/16794866

{PUB} PubChem --- BINOL-derived phosphoramidites in asymmetric hydrogenation: can the presence of a functionality in the amino group influence the catalytic outcome? --- https://pubmed.ncbi.nlm.nih.gov/18362987

{PUB} PubChem --- BINOL‐3,3′‐Triflone N,N‐Dimethyl Phosphoramidites: Through‐Space 19F,31P Spin–Spin Coupling with a Remarkable Dependency on Temperature and Solvent Internal Pressure --- https://pubmed.ncbi.nlm.nih.gov/18642261

{PUB} PubChem --- Fullerene Derivatives Incorporating Phosphoramidous Ylide and

1608-26-0 H42476 Tris(dimethylamino)phosphine
三(二甲胺基)膦

化学属性

Mol. Formula	C6H18N3P
Mol. Weight	163.21
Density	0.898
Refractive index	1.4640 to 1.4670
Boiling Point	160.3°C at 760 mmHg
Flash Point	27°C
TSCA	Yes
Melting Point	-44°C
Solubility	起反应
Stability	对空气敏感;热和湿度敏感
Appearance	yellow liq.

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

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Tris(dimethylamino)phosphine 三(二甲胺基)膦

规格: 99%

化学属性

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