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Allylpalladium(II) chloride dimer 烯丙基氯化钯二聚物

规格: 98%
CAS: 12012-95-2
产品编号: H24051
MDL: MFCD00044874
品牌: INFI
Chemical NameAllylpalladium(II) chloride dimer
MDL NumberMFCD00044874
Synonym 氯化烯丙基钯(II)二聚物 Bis(allyl)dichloropalladium Allyl palladium chloride dimer Diallyldichlorodipalladium 二(烯丙基)二氯二钯(II) Bis(allylchloropalladium) Bis(allyl)dichlorodipalladium 烯丙基氯化钯(II)二聚体,二(烯丙基)二氯二钯(II) 氯化烯丙基钯二聚物 烯丙基氯化钯二聚物 ChemDose™ 片 [PdCl(C3H5)]2 Allylpalladium(II) chloride dimer Bis(allyl)dichlorodipalladium(II) Allylchloropalladium dimer Bis(allyl)dichlorodipalladium Bis(allyl)dichloropalladium Bis(allylchloropalladium) Diallyldichlorodipalladium [PdCl(C3H5)]2 [PdCl(allyl)]2 烯丙基氯化钯(II)二聚体 Allylchloropalladium dimer [PdCl(allyl)]2
EC Number234-579-8
CAS Number12012-95-2
Beilstein Registry Number4124623
PubChem Substance ID61538
Chemical Name Translation烯丙基氯化钯(II)二聚体
Wiswesser Line Notation2U1-PD-G 2
InChIKeyTWKVUTXHANJYGH-UHFFFAOYSA-L
LabNetwork Molecule IDLN00238817
InChIInChI=1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q2*-1;;;2*+2/p-2
  • 1.烯烃对映选择性氢化硅烷化的预催化剂。
  • 2.环丙烯基醋酸盐不对称烷化和氨化的预催化剂。
  • 3.交叉耦联反应催化剂。
  • 4.二聚体可以用作Trost配体。
  • 5.作为高对映选择性烯丙基烷化和氨化的有用前体。
  • 6.烯烃甲锡烷基化催化剂。
  • {ALF} Reacts with lithium enolates of esters, in the presence of CO and excess TMEDA, to give good yields of ɑ-cyclopropyl esters: Angew. Chem. Int. Ed., 31, 234 (1992).
  • {ALF} Used in combination with a chiral diamine to effect displacement of a mesylate with Trimethyl­silyl­ azide, L00173, in the asymmetric synthesis of (+)-pancratistin: J. Am. Chem. Soc., 117, 10143 (1995).
  • 12012-95-2 H24051 Allylpalladium(II) chloride dimer
烯丙基氯化钯二聚物

    化学属性

    Mol. FormulaC6H10Cl2Pd2
    Mol. Weight365.86
    Melting Point120°C (dec.)
    SolubilityVery soluble in dichloromethane and dichloroethane. Slightly soluble in toluene, insoluble in water
    TSCANo
    Density6.68
    Stabilityair sensitive, store cold
    Appearance yellow solid yellow xtl.
    pH:A

    *以上化合物性质及应用等信息仅供参考