Palladium(II) acetate 醋酸钯

规格: 46.9 - 48.5% Pd
CAS: 3375-31-3
产品编号: H15216
MDL: MFCD00012453
品牌: INFI
Chemical NamePalladium diacetate
Synonym Palladium (II) acetate
Beilstein Registry Number6086766
PubChem Substance ID167845
CAS Number3375-31-3
EC Number222-164-4
MDL NumberMFCD00012453
Reaxys-RN3375313
Merck Number6991
Chemical Name Translation醋酸钯
LabNetwork Molecule IDLN00193292
InChIInChI=1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
Canonical SMILESC[Pd]C.O=C=O.O=C=O
IUPAC Namepalladium(2+) diacetate
  • A catalyst for intramolecular coupling.
  • {ALF} Also catalyzes the allylic acetoxylation of cycloalkenes: Org. Synth. Coll., 8, 137 (1993).
  • {PUB} ChemIDplus --- Gigiena i Sanitariya. For English translation, see HYSAAV., 51(12)(88), 1986 ---
  • {ALF} For a brief feature on uses of palladium acetate in synthesis, see: Synlett, 329 (2006).
  • {ALF} For catalysis of the efficient "ligandless" Suzuki cross-coupling of arylboronic acids with aryl iodides, see: J. Org. Chem., 59, 5034 (1994); Org. Synth., 75, 61 (1997).
  • {ALF} For the Heck-type reaction of arenediazonium salts with alkenes, see p-Anisidine, A10946.
  • {PUB} Haz-Map, Information on Hazardous Chemicals and Occupational Diseases --- Hawley - Lewis RJ. _Hawley's Condensed Chemical Dictionary, _15th Ed. New York: John Wiley & Sons, 2007. ---
  • {ALF} In the presence of TBAB, catalyzes direct homocoupling of aryl halides: Tetrahedron Lett., 39, 2559 (1998).
  • {PUB} PubChem|Toxin and Toxin Target Database (T3DB) --- Inhibition of creatine kinase activity and alterations in electrophoretic mobility by palladium ions --- https://pubmed.ncbi.nlm.nih.gov/422942
  • {PUB} PubChem|Toxin and Toxin Target Database (T3DB) --- Inhibition of hydroxyproline synthesis by palladium ions --- https://pubmed.ncbi.nlm.nih.gov/177068
  • {PUB} Toxin and Toxin Target Database (T3DB) --- A21: Smith DR, Kahng MW, Quintanilla-Vega B, Fowler BA: High-affinity renal lead-binding proteins in environmentally-exposed humans. Chem Biol Interact. 1998 Aug 14;115(1):39-52. PMID:9817074 ---
  • {PUB} Toxin and Toxin Target Database (T3DB) --- L794: Wikipedia. Palladium. Last Updated 14 June 2009. http://en.wikipedia.org/wiki/Palladium ---
  • {PUB} Toxin and Toxin Target Database (T3DB) --- L798: International Programme on Chemical Safety (IPCS) INCHEM (2002). Environmental Health Criteria for Palladium. http://www.inchem.org/documents/ehc/ehc/ehc226.htm ---
  • {PUB} Toxin and Toxin Target Database (T3DB) --- L804: Wikipedia. Palladium(II) acetate. Last Updated 22 January 2009. http://en.wikipedia.org/wiki
  • 3375-31-3 H15216 Palladium(II) acetate
醋酸钯

    化学属性

    Mol. FormulaPd(OCOCH3)2
    Mol. Weight224.51
    Melting Point202 - 205 °C
    TSCAYes
    SolubilitySoluble as monomer in glacial acetic acid or as trimer in benzene
    Density0.984
    Appearance golden-brown xtl.

    *以上化合物性质及应用等信息仅供参考