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Ethyl trimethylsilylacetate (三甲基硅基)乙酸乙酯

规格: 98%

CAS: 4071-88-9

产品编号: H99300

MDL: MFCD00009172

品牌: INFI

Chemical Name	Ethyl (Trimethylsilyl)acetate
Synonym	Ethyl 2-(trimethylsilyl)acetate
CAS Number	4071-88-9
PubChem Substance ID	77687
EC Number	223-783-2
Beilstein Registry Number	1755902
MDL Number	MFCD00009172
Reaxys-RN	1755902
Chemical Name Translation	(三甲基硅基)乙酸乙酯
InChIKey	QQFBQBDINHJDMN-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00009627
InChI	InChI=1S/C7H16O2Si/c1-5-9-7(8)6-10(2,3)4/h5-6H2,1-4H3
Canonical SMILES	O=C(OCC)C[Si](C)(C)C

{ALF} Grignard reagents give tertiary carbinols which give 1,1-disubstituted ethylenes by Peterson elimination: Tetrahedron Lett., 23, 1035 (1982). See Appendix 4.

{ALD} Beilstein:4(4)3974

{ALF} Reagent for silylation, under nucleophilic catalysis by TBAF, particularly of sensitive substrates, since the by-product (ethyl acetate) is neutral and filtration is avoided: J. Am. Chem. Soc., 98, 2346 (1976). Alcohols, phenols, ketones, thiols, carboxylic acids and terminal alkynes can be silylated: Bull. Chem. Soc. Jpn., 54, 805 (1981). For conversion of ketones to silyl enol ethers, see: Org. Synth. Coll., 7, 512 (1990).

{uni_hamburg} Short: III/35F

{ALF} Aromatic aldehydes undergo F- promoted Reformatsky-like addition: Tetrahedron Lett., 1699 (1976). Further heating results in Peterson-type elimination to give the ɑß-unsaturated ester: J. Org. Chem., 60, 6582 (1995):

{SNA}

4071-88-9 H99300 Ethyl trimethylsilylacetate
(三甲基硅基)乙酸乙酯

化学属性

Mol. Formula	C7H16O2Si
Mol. Weight	160.29
Refractive index	1.4140 to 1.4180
Boiling Point	157.5°C at 760 mmHg
Density	0.876
Flash Point	48°C
TSCA	No
Solubility	分解
Melting Point	N/A

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Ethyl trimethylsilylacetate (三甲基硅基)乙酸乙酯

规格: 98%

化学属性

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