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Triisopropylsilyl trifluoromethanesulfonate 三异丙基硅基三氟甲磺酸酯

规格: 97%

CAS: 80522-42-5

产品编号: H93282

MDL: MFCD00009913

品牌: INFI

Chemical Name	Triisopropylsilyl trifluoromethanesulfonate
MDL Number	MFCD00009913
Synonym	TRI ISOPROPYLSILYL TRIFLUOROMETHANESULPHONATE 98% TRIISOPROPYLSILYL TRIFLATE TIPS-OTF TRIISOPROPYLSILYL TRIFLUOROMETHANESULFONATE 97% TRIISOPROPYLSILYL TRIFLUOROMETHANESULFONATE TIPS TRIFLATE TIPS triflate, Trifluoromethanesulfonic acid triisopropylsilyl ester, Triisopropylsilyl triflate, Wacker Silane IP3-triflate TRIFLUOROMETHANESULFONIC ACID TRIISOPROPYLSILYL ESTER TRIISOPROPYLSILYL TRIFLUOROMETHANESULPHONATE TIPS 三氟甲磺酸酯三异丙基甲硅烷基三氟甲磺酸酯三氟甲磺酸三异丙基硅基酯 TIPS-OTf Triisopropyl(trifluoromethylsulfonyloxy)silane WACKER SILANE IP3-TRIFLATE TIPS triflate, Trifluoromethanesulfonic acid triisopropylsilyl ester, Triisopropylsilyl triflate 三异丙基硅基三氟甲磺酸酯 SILANE IP3-TRIFLATE
EC Number	000-000-0
CAS Number	80522-42-5
Beilstein Registry Number	3591541
PubChem Substance ID	87577345
Reaxys-RN	3591541
Chemical Name Translation	三异丙基甲硅烷基三氟甲烷磺酸盐
LabNetwork Molecule ID	LN00009591

{ALF} A method for protecting both H atoms of a primary amine consists of formation of the succinimide, followed by enolsilylation with TIPS-OTf, to form the 2,5-bis(triisopropylsiloxy)pyrroles. Deprotection can be effected by desilylation with dilute HCl, followed by hydrazinolysis: Tetrahedron Lett., 38, 2617 (1997).

{ALF} For a comprehensive review of the TIPS group in organic chemistry, see: Chem. Rev., 95, 1009 (1995).

{ALF}

{ALF} Reagent for introduction of the triisopropylsilyl (TIPS) group: Tetrahedron Lett., 22, 3455 (1981); compare Chlorotriisopropylsilane, A17376, and Appendix 4. For general reactions of silyl triflates, see Trimethylsilyl trifluoromethanesulfonate, A12535.

{ALF} For use in the synthesis of 2-substituted benzothiopyran-4-ones, see: Synlett, 182 (1996):

80522-42-5 H93282 Triisopropylsilyl trifluoromethanesulfonate
三异丙基硅基三氟甲磺酸酯

化学属性

Mol. Formula	C10H21F3O3SSi
Mol. Weight	306
Density	1.14
Refractive index	1.4130 to 1.4160
Flash Point	100°C(lit.)
TSCA	No
Boiling Point	45-46
pH	:A

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Triisopropylsilyl trifluoromethanesulfonate 三异丙基硅基三氟甲磺酸酯

规格: 97%

化学属性

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