DoMole-安徽敦茂科技

Tebbe reagent Tebbe试剂

规格: 0.5 M solution in toluene, SpcSeal

CAS: 67719-69-1

产品编号: H90526

MDL: MFCD00151575

品牌: INFI

Chemical Name	TEBBE Reagent
Synonym	Tebbe Reagent TEBBE 试剂溶液双(环戊二烯基)-μ-氯化(二甲基铝)-μ-亚甲基钛
MDL Number	MFCD00151575
PubChem Substance ID	24863730
CAS Number	67719-69-1
Merck Number	14,9091
Chemical Name Translation	试剂TEBBE

GHS Symbol

WGK Germany	3
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P301+P310 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P305+P351+P338 P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。 P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word	Danger
Hazard statements
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤 H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命 H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕 H225 Highly flammable liquid and vapour 高度易燃液体和蒸气 H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害 H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Hazard Codes	F,C
Personal Protective Equipment	Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）； S20 When using do not eat or drink 使用时，不得进食，饮水； S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥； S33 Take precautionary measures against static discharges 对静电采取预防措施； S30 Never add water to this product 切勿将水加入该产品中； S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S9 Keep container in a well-ventilated place 保持容器在通风良好的场所； S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签； S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟； S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾； S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水” S8 Keep container dry 保持容器干燥；
UN Number	UN3399
Risk Statements
R11 Highly flammable 非常易燃 R48/20 R14 Reacts violently with water 遇水会猛烈反应 R34 Causes burns 会导致灼伤 R63 Possible risk of harm to the unborn child 可能危害未出生婴儿 R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官 R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥 R20 Harmful by inhalation 吸入有害
Storage condition	Air & Moisture Sensitive
Packing Group	II
Restrict	危险品

{SA}

1. Synthesis , 165, (1991)

{SA}

Bioorg. Med. Chem. 11 , 2489-2497, (2003) 摘要

{SA}

{SA} Org. Lett. 7 , 1645, (2005) 摘要

{SA}

{SA} Merck 14 ,9091

{SA}

Fieser 8 ,83 / Fieser 10 ,87 / Fieser 11 ,52 / Fieser 12 ,54 / Fieser 13 ,71 / Fieser 15 ,79 / Fieser 16 ,70 / Fieser 17 ,69

{SA}

Structure Index 1 , 494:B:5

化学属性

Mol. Formula	C13H18AlClTi
Mol. Weight	284.58
Density	0.927 g/mL at 25 °C
Flash Point	1°(34°F)
TSCA	No

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Tebbe reagent Tebbe试剂

规格: 0.5 M solution in toluene, SpcSeal

化学属性

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