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Bis(triphenylphosphine)copper(I) borohydride 双(三苯基膦)硼氢化铜

规格: 90%
CAS: 16903-61-0
产品编号: H89874
MDL: MFCD00013219
品牌: INFI
Chemical NameBis(Triphenylphosphine)Copper(I) Borohydride
MDL NumberMFCD00013219
PubChem Substance ID87564081
EC Number240-951-0
Synonym Bis(triphenylphosphine)copper(I) tetrahydridoborate 双(三苯基膦)硼氢化铜(I) Bis(triphenylphosphine)copper(I) borohydride
CAS Number16903-61-0
Reaxys-RN14867991
Chemical Name Translation双(三苯基膦)硼氢化亚铜
Beilstein Registry Number14867991
GHS Symbol
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
  • S8 Keep container dry 保持容器干燥；
    Packing GroupIII
    UN Number 2813 UN2813
    Risk Statements
    • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      Storage condition Moisture Sensitive
      Signal word Warning
      Hazard statements
      • H315 Causes skin irritation 会刺激皮肤
        Precautionary statements
        • P231+P232
        • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
        • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
        • P305+P351+P338
        • P405 Store locked up. 上锁保管。
        • P501a
          Hazard Codes 4.3
        • {ALF} Specific reagent for reduction of acid chlorides to aldehydes: Tetrahedron Lett., 1437 (1978); 975 (1979). Also reduces sulfonylhydrazones to alkanes: Tetrahedron Lett., 4031 (1980), and aryl azides to amines: J. Chem. Res. (Synop.), 17 (1981).
        • {ALF} In the presence of Lewis acids or HCl, reduces carbonyl compounds with good stereo- and chemo-selectivity, e.g. aldehydes in the presence of ketones: Tetrahedron Lett., 22, 675 (1981).
          • 16903-61-0 H89874 Bis(triphenylphosphine)copper(I) borohydride 双(三苯基膦)硼氢化铜

          化学属性

          Mol. FormulaC36H34BCuP2
          Mol. Weight603
          Melting Point150
          TSCANo

          *以上化合物性质及应用等信息仅供参考

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