{ALF} Carbonyl compounds can be converted to their silyl enol ethers, e.g. with triethylamine in DMF: Org. Synth. Coll., 6, 327 (1988); 7, 424 (1990); 8, 460 (1993); or using catalysis with NaI: Org. Synth. Coll., 9, 573 (1998).

{ALF} Conjugated enones give trimethylsilyloxydienes. For examples, see: Org. Synth. Coll., 6, 445 (1988); 7, 282 (1990). TMS chloride, LiBr and trimethylamine in THF is a convenient system for silylation of enones: Acta Chem. Scand., 43, 188 (1989). The same combination converts ɑ- and ß-diketones to their bis silyl enol ethers: Acta Chem. Scand., 43, 304 (1989). See also Trimethyl­silyl­ trifluoromethanesulfonate, A12535.

{ALF} For cleavage of ethers, see Sodium iodide, A15480.

{ALF} For facile O-silylation of tertiary alcohols in the presence of Mg metal, see: Synlett, 1025 (2000).

{ALF} For further details and reviews, see Appendix 4.

{ALD} Merck: 14,10311

{ALD} Merck: 14,10311 Beilstein:4(3)1857

{PUB} P

{PUB} PubC

{PUB} PubChem --- 1,4‐Addition of Bis(iodozincio)methane to α,β‐Unsaturated Ketones: Chemical and Theoretical/Computational Studies --- https://pubmed.ncbi.nlm.nih.gov/20645344

{PUB} PubChem --- Caenorhabditis elegans Battling Starvation Stress: Low Levels of Ethanol Prolong Lifespan in L1 Larvae --- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3261173

{PUB} PubChem --- Selective Benzylic and Allylic Alkylation of Protic Nucleophiles with Sulfonamides through Double Lewis Acid Catalyzed Cleavage of sp3 Carbon–Nitrogen Bonds --- https://pubmed.ncbi.nlm.nih.gov/19035590

{PUB} PubChem|Springer Nature --- A New Class of 5-Fluoro-2′-deoxyuridine Prodrugs Conjugated with a Tumor-Homing Cyclic Peptide CNGRC by Ester Linkers: Synthesis, Reactivity, and Tumor-Cell–Selective Cytotoxicity --- https://pubmed.ncbi.nlm.nih.gov/15835743

{PUB} PubChem|Springer Nature --- A microfluidic traps system supporting prolonged culture of human embryonic stem cells aggregates --- https://pubmed.ncbi.nlm.nih.gov/20665114