DoMole-安徽敦茂科技

Palladium(II) chloride 氯化钯(II)

规格: 99%, pd＞59.5%

CAS: 7647-10-1

产品编号: H78811

MDL: MFCD00003558

品牌: INFI

Chemical Name	Palladium(II) Chloride
Alfabeta Name	PALLADIUMCHLORIDE II()
PubChem Substance ID	24290
EC Number	231-596-2
Merck Number	6990
Synonym	Palladium(II) chloride {LY} Palladium(II) chloride {} {LY} Palladium(II) chloride {} {} {LY} Palladium(II) chloride {} {} {} {LY} Palladium(II) chloride {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {}
Beilstein Registry Number	2384789
Chemical Name Translation	氯化钯
Wiswesser Line Notation	PD G2
LabNetwork Molecule ID	LN00170222
InChI	InChI=1S/2ClH.Pd/h2*1H;/q;;+2/p-2
MDL Number	MFCD00003558
CAS Number	7647-10-1
Canonical SMILES	Cl[Pd]Cl

GHS Symbol

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 880 mg/kg/75W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Blood - leukemia
REFERENCE :
   JONUAI Journal of Nutrition.  (Subscription Dept., 9650 Rockville Pike,
   Bethesda, MD 20014) V.1-    1928-  Volume(issue)/page/year: 101,1431,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 10,63,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ATSUDG Archives of Toxicology, Supplement.  (Springer-Verlag New York, Inc.,
   Service Center, 44 Hartz Way, Secaucus, NJ 07094)  No.1-    1978-
   Volume(issue)/page/year: 13,357,1989

TYPE OF TEST

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 87 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ATSUDG Archives of Toxicology, Supplement.  (Springer-Verlag New York, Inc.,
   Service Center, 44 Hartz Way, Secaucus, NJ 07094)  No.1-    1978-
   Volume(issue)/page/year: 13,357,1989

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 18600 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BSIBAC Bolletino della Societe Italiana di Biologia Sperimentale.  (Casa
   Editrice Idelson, Via A. de Gasperi, 55, 80133 Naples, Italy)  V.2- 1927- 
   Volume(issue)/page/year: 8,1154,1933

TYPE OF TEST            : LD5

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 600 umol/L
REFERENCE :
   IAAAAM International Archives of Allergy and Applied Immunology.  (S. Karger
   Pub., Inc., 79 Fifth Ave., New York, NY 10003)  V.1-    1950-
   Volume(issue)/page/year: 79,83,1986

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 3546 ug/kg
SEX/DURATION            : male 30 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
   JRPFA4 Journal of Reproduction and Fertility.  (Biochemical Soc. Book Depot,
   POB 32, Commerce Way, Colchester, Essex CO2 8HP, UK)  V.1-    1960-
   Volume(issue)/page/year: 7,21,1964

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intratesticular
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 3546 ug/kg
SEX/DURATION            : male 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
   JRPFA4 Journal of Reproduction and Fertility.  (Biochemical Soc. Book Depot,
   POB 32, Commerce Way, Colchester, Essex CO2 8HP, UK)  V.1-    1960-
   Volume(issue)/page/year: 7,21,1964

Warnings	IRRITANT
WGK Germany	3
Hazard Codes	6.1 C,Xi,T+ C,Xn T T+
Hazard statements
H290 May be corrosive to metals 可能腐蚀金属。 H301 Toxic if swallowed 吞食有毒 H302 Harmful if swallowed 吞食有害 H303 May be harmfully swallowed 吞食可能有害 H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤 H315 Causes skin irritation 会刺激皮肤 H317 May cause an allergic skin reaction 可能导致皮肤过敏 H318 Causes serious eye damage 严重伤害眼睛 H319 Causes serious eye irritation 严重刺激眼睛 H335 May cause respiratory irritation 可能导致呼吸道刺激 H400 Verytoxictoaquaticlife 对水生生物毒性非常大。 H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RTECS	RT3500000
Precautionary statements
P234 Keep only in original container. 只保留在原来的容器中。 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P264+P265 P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。 P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。 P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。 P273 Avoid release to the environment. 避免释放到环境中。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P301+P310 P301+P312 P301+P317 P302+P352 P302+P352+P333+P313+P362+P364 P304+P340 P305+P351+P338 P305+P351+P338+P337+P313 P305+P354+P338 P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。 P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。 P317 P319 P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。 P330 Rinse mouth. 漱口 P332+P313 P332+P317 P333+P313 P337+P313 P337+P317 P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用 P362+P364 P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。 P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。 P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。 P403+P233 P404 Store in a closed container. 贮存于密闭容器中。 P405 Store locked up. 上锁保管。 P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。 P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word	Danger
Safety Statements
S24 Avoid contact with skin 避免皮肤接触； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服； S27/28 S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗； S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S37 Wear suitable gloves 戴适当手套； S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）； S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
UN Number	3288
Risk Statements
R22 Harmful if swallowed 吞咽有害 R25 Toxic if swallowed 吞咽有毒 R28 Very toxic if swallowed 吞咽极毒 R34 Causes burns 会导致灼伤 R35 Causes severe burns 会导致严重灼伤 R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用 R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应 R50/53
Packing Group	III
Storage condition	Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class	8

1、点滴测定钯、汞、铊和碘，提纯稀有气味，氯化钯试纸检验一氧化碳、检定钴。

2、催化剂，末端烯径（α-烯径）生成甲基酮的氧化催化。

3、通过Wacker反应，在水溶液中用空气作氧化剂，使烯径氧化成醛。

4、用于合成半导体含金属聚合体，该聚合体具有聚吡咯骨架，符合能量最小且接近平面。

{ALFA} For use in the microwave accelerated Heck coupling reaction of aryl halides in the ionic liquid 1-n-Butyl-3-methylimidazolium hexafluorophosphate, L19086, see: J. Org. Chem., 67, 6243 (2002).

{ALFA} In combination with benzoquinone as reoxidant, N-methylarylamines add to Michael acceptors to give enamines: J. Org. Chem., 46, 2561 (1981).

{ALFA} In the presence of triphenylphosphine and MeLi, a Pd(0) species is generated which catalyzes the coupling of organolithium reagents with aryl or vinyl halides. For tabulated results, see: Org. Synth. Coll., 7, 172 (1990):

{ALD} Merck: 14,6990

{SA} Miki, K.; Nishino, F. et al. J. Am. Chem. Soc. 124 , 5260, (2004)

{uni_hamburg} Short: III/20b

{ALFA} Terminal olefins can be oxygenated to ketones using a Cu(I) catalyst in the presence of a catalytic amount of PdCl2 (the Wacker process): Org. Synth. Coll., 7, 137 (1990). For an example in which the product is readily cyclized to give a useful terpenoid synthon, see: Org. Synth. Coll., 8, 208 (1993):

7647-10-1 H78811 Palladium(II) chloride
氯化钯(II)

化学属性

TSCA	Yes
Solubility	Soluble in dilute mineral acids, aqueous metal halides
Mol. Formula	Cl2Pd
Mol. Weight	177.33
Density	4
Appearance	rust colored xtl.
Stability	hygroscopic
Melting Point	678-680°C

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Palladium(II) chloride 氯化钯(II)

规格: 99%, pd＞59.5%

化学属性

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