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Palladium(II) chloride 氯化钯(II)

规格: 99%, pd>59.5%
CAS: 7647-10-1
产品编号: H78811
MDL: MFCD00003558
品牌: INFI
Chemical NamePalladium chloride
CAS Number7647-10-1
Alfabeta NamePALLADIUMCHLORIDE II()
MDL NumberMFCD00003558
PubChem Substance ID24290
EC Number231-596-2
Merck Number6990
Synonym Palladium Dichloride 异类催化剂放映试剂盒 氯化钯(II), 99.9% (METALS BASIS), PD 59.5% MIN Dichloropalladium 氯化钯(II)溶液, PD 9.0-11.0% W/W ( PdCl2 Palladium chloride, pdcl2 氯化钯(II)溶液, PD 20-25% W/W (CONT. PD) Palladium(2+) chloride PALLADIUM (II) CHLORIDE 99.9% (METALS BASIS) PD 59.5% MIN palladium (II) chloride 套装单耦合器具1A Enplate Activator 440 PALLADIUM(II) CHLORIDE NCI-C60184 Palladiumdichl Palladium (II) chloride Palladous chloride Palladouschlor 二氯化钯,氯化亚钯 氯化钯(II);二氯化钯 Palladium chloride (PdCl2) palladium(ii) chloride anhydrous PALLADIUM(II) CHLORIDE, 5 WT.
Beilstein Registry Number2384789
Chemical Name Translation二氯化钯
Wiswesser Line NotationPD G2
LabNetwork Molecule IDLN00170222
InChIInChI=1S/2ClH.Pd/h2*1H;/q;;+2/p-2
MDL NumberMFCD00003558
CAS Number7647-10-1
GHS Symbol
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 880 mg/kg/75W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Blood - leukemia
REFERENCE :
   JONUAI Journal of Nutrition.  (Subscription Dept., 9650 Rockville Pike,
   Bethesda, MD 20014) V.1-    1928-  Volume(issue)/page/year: 101,1431,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 10,63,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ATSUDG Archives of Toxicology, Supplement.  (Springer-Verlag New York, Inc.,
   Service Center, 44 Hartz Way, Secaucus, NJ 07094)  No.1-    1978-
   Volume(issue)/page/year: 13,357,1989

TYPE OF TEST

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 87 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ATSUDG Archives of Toxicology, Supplement.  (Springer-Verlag New York, Inc.,
   Service Center, 44 Hartz Way, Secaucus, NJ 07094)  No.1-    1978-
   Volume(issue)/page/year: 13,357,1989

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 18600 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BSIBAC Bolletino della Societe Italiana di Biologia Sperimentale.  (Casa
   Editrice Idelson, Via A. de Gasperi, 55, 80133 Naples, Italy)  V.2- 1927- 
   Volume(issue)/page/year: 8,1154,1933

TYPE OF TEST            : LD5

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 600 umol/L
REFERENCE :
   IAAAAM International Archives of Allergy and Applied Immunology.  (S. Karger
   Pub., Inc., 79 Fifth Ave., New York, NY 10003)  V.1-    1950-
   Volume(issue)/page/year: 79,83,1986

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 3546 ug/kg
SEX/DURATION            : male 30 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
   JRPFA4 Journal of Reproduction and Fertility.  (Biochemical Soc. Book Depot,
   POB 32, Commerce Way, Colchester, Essex CO2 8HP, UK)  V.1-    1960-
   Volume(issue)/page/year: 7,21,1964

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intratesticular
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 3546 ug/kg
SEX/DURATION            : male 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
   JRPFA4 Journal of Reproduction and Fertility.  (Biochemical Soc. Book Depot,
   POB 32, Commerce Way, Colchester, Essex CO2 8HP, UK)  V.1-    1960-
   Volume(issue)/page/year: 7,21,1964

Warnings IRRITANT
WGK Germany3
Hazard Codes 6.1 C,Xi,T+ C,Xn T T+
Hazard statements
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H301 Toxic if swallowed 吞食有毒
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H303 May be harmfully swallowed 吞食可能有害
    Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
    RTECSRT3500000
    Precautionary statements
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P301+P310
    • P302+P352+P333+P313+P362+P364
    • P305+P351+P338+P337+P313
    • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
    • P330 Rinse mouth. 漱口
    • P333+P313
      Signal word Danger
      Safety Statements
      • S24 Avoid contact with skin 避免皮肤接触;
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
      • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
      • S27/28
      • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
      • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
      • S37 Wear suitable gloves 戴适当手套;
      • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
      • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
        UN Number 3288
        Risk Statements
        • R22 Harmful if swallowed 吞咽有害
        • R25 Toxic if swallowed 吞咽有毒
        • R28 Very toxic if swallowed 吞咽极毒
        • R34 Causes burns 会导致灼伤
        • R35 Causes severe burns 会导致严重灼伤
        • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
        • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
        • R50/53
          Packing GroupIII
          Storage condition 储存温度2-8℃ 密封干燥保存。 储存温度2-8℃,充氩保存
          Hazard Class8
        • 1、点滴测定钯、汞、铊和碘,提纯稀有气味,氯化钯试纸检验一氧化碳、检定钴。
        • 2、催化剂,末端烯径(α-烯径)生成甲基酮的氧化催化。
        • 3、通过Wacker反应,在水溶液中用空气作氧化剂,使烯径氧化成醛。
        • 4、用于合成半导体含金属聚合体,该聚合体具有聚吡咯骨架,符合能量最小且接近平面。
        • {ALFA} For use in the microwave accelerated Heck coupling reaction of aryl halides in the ionic liquid 1-n-Butyl-3-methyl­imidazolium hexafluorophosphate, L19086, see: J. Org. Chem., 67, 6243 (2002).
        • {ALFA} In combination with benzoquinone as reoxidant, N-methylarylamines add to Michael acceptors to give enamines: J. Org. Chem., 46, 2561 (1981).
        • {ALFA} In the presence of triphenylphosphine and MeLi, a Pd(0) species is generated which catalyzes the coupling of organolithium reagents with aryl or vinyl halides. For tabulated results, see: Org. Synth. Coll., 7, 172 (1990):
        • {ALD} Merck: 14,6990
        • {SA} Miki, K.; Nishino, F. et al. J. Am. Chem. Soc. 124 , 5260, (2004)
        • {uni_hamburg} Short: III/20b
        • {ALFA} Terminal olefins can be oxygenated to ketones using a Cu(I) catalyst in the presence of a catalytic amount of PdCl2 (the Wacker process): Org. Synth. Coll., 7, 137 (1990). For an example in which the product is readily cyclized to give a useful terpenoid synthon, see: Org. Synth. Coll., 8, 208 (1993):
        • 7647-10-1 H78811 Palladium(II) chloride
氯化钯(II)

          化学属性

          Mol. FormulaPdCl2
          Mol. Weight177.32
          Density4
          Melting Point678-680
          TSCAYes
          SolubilitySoluble in dilute mineral acids, aqueous metal halides
          Appearance 红褐色结晶粉末,溶于水、盐酸、乙醇、丙酮和氢溴酸。
          Stability易吸潮
          Mol. FormulaPdCl2
          Mol. Weight177
          Density4
          Appearance rust colored xtl.
          Stabilityhygroscopic
          Melting Point678-680