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Bis(2-oxo-3-oxazolidinyl)phosphinic chloride 二(2-氧代-3-唑烷基)次膦酰氯

规格: 97%

CAS: 68641-49-6

产品编号: H78250

MDL: MFCD00010077

品牌: INFI

Chemical Name	Bis(2-oxo-3-oxazolidinyl)phosphinic chloride
MDL Number	MFCD00010077
Synonym	BOP-Cl Bis(2-oxo-3-oxazolidinyl)phosphinic chloride Bis(2-oxo-3-oxazolidinyl)phosphorodiamidic Chloride 双(2-氧代-3-噁唑烷基)次磷酰氯双（2-氧代-3-恶唑烷基）次磷酰氯
CAS Number	68641-49-6
Beilstein Registry Number	87564149
PubChem Substance ID	87564149
EC Number	250-023-7
Reaxys-RN	3654596
Chemical Name Translation	二(2-氧代-3-唑烷基)次膦酰氯
InChIKey	KLDLRDSRCMJKGM-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00009083

GHS Symbol

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 170,23,1986

RTECS	SZ5871000
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Packing Group	II
UN Number	3261
Risk Statements
R34 Causes burns 会导致灼伤
Storage condition	Moisture Sensitive 阴凉干燥处保存；易吸潮。
WGK Germany	3
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。 P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P301+P330+P331+P310 P303+P361+P353 P304+P340+P310 P305+P351+P338 P305+P351+P338+P310 P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。 P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
H290 May be corrosive to metals 可能腐蚀金属。 H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Signal word	Danger
Personal Protective Equipment	Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes	8 C
Hazard Class	8

多肽缩合剂。适宜于因有空间位阻而不能与碳二亚胺类缩合剂反应的情形。

{ALF} For use in the direct selective 5'-acylation of nucleosides by carboxylic acids, (without 3'-protection), see: Tetrahedron, 44, 229 (1988). For high yield dehydration of carboxylic acids to anhydrides, see: Synthesis, 616 (1981). Also used in macrolide cyclization: J. Am. Chem. Soc., 104, 6818 (1982), and in formation of acyclic esters: Synth. Commun., 14, 515 (1984).

{ALF}

{ALF} Coupling reagent for which the rates of reaction with various nucleophiles are sufficiently different to permit a genuine "one-step" coupling of carboxylic acids with amines: Synthesis, 547 (1980). Particularly suitable for coupling N-alkyl amino acids: J. Org. Chem., 51, 3350 (1986). For discussion of strategies for one-step coupling in synthesis of amides, see: Synthesis, 413 (1984), and of the scope and limitations of the reagent in peptide coupling, see: Int. J. Pept. Prot. Res., 29, 574 (1987); J. Org. Chem., 55, 2895 (1990). See also Appendix 6.

{ALF} The mixed anhydride formed with carboxylic acids adds to imines to give ß-lactams: Synthesis, 63 (1982):

{ALF} These are also formed in high yield by cyclization of ß-amino acids: Bull. Korean Chem. Soc., 12, 457 (1991).

68641-49-6 H78250 Bis(2-oxo-3-oxazolidinyl)phosphinic chloride
二(2-氧代-3-唑烷基)次膦酰氯

化学属性

Mol. Formula	C6H8ClN2O5P
Mol. Weight	255
Melting Point	191
TSCA	No
Density	1.71
Stability	易吸潮

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Bis(2-oxo-3-oxazolidinyl)phosphinic chloride 二(2-氧代-3-唑烷基)次膦酰氯

规格: 97%

化学属性

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