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Aluminum chloride 无水氯化铝

规格: 99%
CAS: 7446-70-0
产品编号: H75929
MDL: MFCD00003422
品牌: INFI
Chemical NameAluminum Trichloride
PubChem Substance ID24012
Synonym ALUMINIUM CHLORIDE (III) ALUMINUM AA STANDARD CONCENTRATE ALUMINUM CHLORIDE ALUMINUM TRICHLORIDE ALUMINUM(III) CHLORIDE AlCl3 Alluminio(cloruro di) Aluminium trichloride Aluminiumchlorid Aluminum trichloride Anhydrous Aluminum Chloride Drysol Trichloroaluminum alluminio(clorurodi) aluminiumchloridesolutions aluminum chloride aluminum chloride hexahydrate aluminum chloride, anhydrous aluminum trichloride 三氯化铝 溶液 氯化铝 氯化铝, 无水, 99.985%B(METALS BASIS) 纳米铝粉
EC Number231-208-1
Merck Number337
Chemical Name Translation无水氯化铝(易涉毒)
Wiswesser Line NotationAL G3
LabNetwork Molecule IDLN00197168
MDL NumberMFCD00003422
CAS Number7446-70-0
InChIInChI=1S/Al.3ClH/h;3*1H/q+3;;;/p-3
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1130 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 30(4),16,1965

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 315 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 43(4),12,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EPASR* United States Environmental Protection Agency, Office of Pesticides
   and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
   Washington, DC 20460)  History unknown.  Volume(issue)/page/year:
   8EHQ-0191-1109

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3450 mg/kg
TOXIC EFFECTS :
   Brain and Coverings - other degenerative changes
   Gastrointestinal - other changes
   Kidney, Ureter, Bladder - hematuria
REFERENCE :
   SRTCAC Science Reports of the Research Institutes, Tohoku University, Series
   C: Medicine. (Tohoku University, Research Institute for Tubercu

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Rodent - rat Ascites tumor
DOSE/DURATION           : 500 umol/L
REFERENCE :
   JBCHA3 Journal of Biological Chemistry.  (428 E. Preston St., Baltimore, MD
   21202)  V.1-    1905-  Volume(issue)/page/year: 261,3370,1986

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 444 mg/kg
REFERENCE :
   NULSAK Nucleus (Calcutta).  (Dr. A.K. Sharma, Centre of Advanced Studies in
   Cell and Chromosome Research, Calcutta, 35 Baliygunge Circular Rd., Calcutta
   700 019, India)  V.1-    1958-  Volume(issue)/page/year: 15,180,1972

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 500 mg/kg
SEX/DURATION            : female 14-18 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   ANANAU Anatomischer Anzeiger.  (VEB Gustav Fischer Verlag, Postfach 176,
   Jena DDR-6900, Ger. Dem. Rep.)  V.1-    1886-  Volume(issue)/page/year:
   138,365,1975

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 425 mg/kg
SEX/DURATION            : multigenerations
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight
   gain)
REFERENCE :
   BJIMAG British Journal of Industrial Medicine.  (British Medical Journal,
   Box 560B, Kennebunkport, ME 04046)  V.1-    1944-  Volume(issue)/page/year:
   23,305,1966

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 5723 mg/kg
SEX/DURATION            : female 1-21 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - other neonatal measures or effects
   Reproductive - Effects on Newborn - behavioral
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 40,21,1989

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 11512 mg/kg
SEX/DURATION            : female 8-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - weaning or lactation index (e.g., #

WGK Germany1
Hazard Codes 8 F,T T
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H303 May be harmfully swallowed 吞食可能有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
    Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Eyeshields, Gloves Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    Precautionary statements
    • P201 Obtain special instructions before use. 使用前获取专门指示。
    • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P234 Keep only in original container. 只保留在原来的容器中。
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
    • P301+P312
    • P301+P330+P331
    • P303+P361+P353
    • P303+P361+P353+P310+P363
    • P304+P340
    • P305+P351+P338
    • P308+P313
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
    • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
    • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
    • P330 Rinse mouth. 漱口
    • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
    • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
    • P404 Store in a closed container. 贮存于密闭容器中。
    • P405 Store locked up. 上锁保管。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      RTECSBD0525000
      Safety Statements
      • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
      • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
      • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中,保持干燥;
        Packing GroupII
        UN Number 1726
        Risk Statements
        • R11 Highly flammable 非常易燃
        • R14 Reacts violently with water 遇水会猛烈反应
        • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
        • R34 Causes burns 会导致灼伤
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
        • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
        • R48/20
        • R48/23/24
        • R48/25
        • R51/53
        • R52 Harmful to aquatic organisms 对水生生物有害
        • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
          Storage condition Moisture Sensitive 防潮、密封充氩保存。 2-8°C
          Hazard Class8
          Warnings 危化品目录(2015)
          Restrict 危险品
        • 有机合成催化剂,强脱水剂,酸催化剂,制造人造橡胶、塑料、润滑剂等的催化剂,冶金,石油裂化。
        • {ALD} Merck: 14,323
        • {ALD} Merck: 14,337
        • 7446-70-0 H75929 Aluminum chloride
无水氯化铝

          化学属性

          Vapor Pressure1 mmHg ( 100 °C)
          TSCAYes
          SolubilityReacts violently with water with liberation of heat; soluble in HCl, ether, ethanol
          Flash Point88 °C
          Mol. FormulaAlCl3
          Mol. Weight133
          Density2.44
          Appearance -20 mesh white to yellow pwdr.
          Stabilitymoisture sensitive
          Boiling Point180°C subl.
          Melting Point190

          *以上化合物性质及应用等信息仅供参考