{ALF} Catalyst for an improved version of the Oppenauer oxidation of primary and secondary alcohols to aldehydes and ketones (see Aluminum tert-butoxide, A16954, and Aluminum isopropoxide, 14007) which proceeds at room temperature in the presence of substoichiometric amounts of the catalyst, a moderate excess of chloral as the hydride acceptor and 3-an

{ALFA} Catalyst for an improved version of the Oppenauer oxidation of primary and secondary alcohols to aldehydes and ketones (see Aluminum tert-butoxide, A16954, and Aluminum isopropoxide, 14007) which proceeds at room temperature in the presence of substoichiometric amounts of the catalyst, a moderate excess of chloral as the hydride acceptor and 3-angstrom molecular sieves to prevent hydrolysis of the catalyst: Synthesis, 1341 (1996). In a related method, the reagent is used catalytically in the presence of t-butyl hydroperoxide or cumene hydroperoxide as the hydride acceptor under anhydrous conditions: J. Org. Chem., 61, 1467 (1996).

{uni_hamburg} Short: IV/18A

{uni_hamburg} Short: IV/20B

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