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Hexacarbonylchromium 六羰基铬

规格: 99%

CAS: 13007-92-6

产品编号: H66627

MDL: MFCD00010945

品牌: INFI

Chemical Name	Chromium(0) Hexacarbonyl
Synonym	Chromium carbonyl (Cr(CO)6) Chromium carbonyl (cr(co)6), (oc-6-11)- Chromhexacarbonyl Chromiumhexacarbonyl Hexacarbonylchromium(0) 六羰基铬 (OC-6-11)-Chromiumcarbonyl Hexacarbonylchromium: (Chromium hexacarbonyl) Hexacarbonyl chromium (oc-6-11)-chromiumcarbonyl(cr(co)6 CHROMIUM CARBONYL Hexacarbonylchromium(0) Chronium hexacarbonyl(99%) Cr(CO)6 CHROMIUM(0) HEXACARBONYL, 98% Chromium carbonyl Hexacarbonylchromium Chromiumcarbonyl~Hexacarbonylchromium Chromiumcarbonyl,99% Chromium carbonyl (Cr(CO)6), (OC-6-11)- Chromcarbonyl CHROMIUM HEXACARBONYL Chromiumcarbonyl(Cr(CO)6),(OC-6-11)- chromiumcarbonyl(oc-6-11) Chromium hexacarbonyl (OC-6-11)-Chromium carbonyl (Cr(CO)₆) HEXACARBONYLCHROMIUM Chromiumcarbonyl(Cr(CO)6) Hexacarbonylchromium Chromium carbonyl Chromium hexacarbonyl, 99+% CHROMIUM(0) HEXACARBONYL TECH. 96 % 六羰基铬 Chromium carbonyl (OC-6-11)
PubChem Substance ID	24854484
EC Number	235-852-4
Chemical Name Translation	六羰基铬
Wiswesser Line Notation	CR C-O6
MDL Number	MFCD00010945
CAS Number	13007-92-6

GHS Symbol

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Implant
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 75 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Tumorigenic - tumors at site of application
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   37,1476,1977

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 35 mg/m3/30M
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - tetany
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 20(2),38,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 230 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 20(2),38,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 30 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AQMOAC Air Quality Monographs.  (Washington, DC)  No.69-1 - No.75-25,
   1969-75(?).  Discontinued.  Volume(issue)/page/year: #70-15,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 150 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdu

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 2 gm/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 241,175,1990

WGK Germany	3
Hazard statements
H301 Toxic if swallowed 吞食有毒
RTECS	GB5075000
Precautionary statements
P301+P310
Signal word	Danger
Safety Statements
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）； S36 Wear suitable protective clothing 穿戴适当的防护服； S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
Packing Group	III
UN Number	3466 UN3466
Risk Statements
R5 Heating may cause an explosion 加热会引起爆炸 R22 Harmful if swallowed 吞咽有害 R44 Risk of explosion if heated under confinement 密封下加热有爆炸危险 R50/53 R49 May cause cancer by inhalation 吸入会致癌 R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应 R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Storage condition	Light Sensitive
Hazard Codes	Xn T,N
Hazard Class	6.1

{uni_hamburg} Short: II/25D

{

{ALD} Merck: 14,2232

{ALF} Reaction with organolithiums gives Fischer carbene complexes: Chem. Ber., 101, 954 (1968); Org. Synth. Coll., 8, 216 (1993). These react with alkynes to give ɑ-naphthol chromium tricarbonyl complexes (Dotz reaction): Angew. Chem. Int. Ed., 14, 644 (1975); 23, 587 (1984). For an example, see: Org. Synth. Coll., 9, 1 (1998):

{uni_hamburg} Short: III/35D5

{ALF} For discussion of the mechanism of the Dotz reaction, see: Organometallics, 14, 1492 (1998); 15, 2590 (1999).

{ALF} On heating with benzene derivatives readily forms (arene)Cr(CO)3 complexes, which are often stable, crystalline solids: J. Chem. Soc., 551 (1959). Complex formation is retarded by the presence of electron-withdrawing or bulky substituents. The strongly electron-withdrawing nature of the Cr(CO)3 group itself activates the aromatic system to metallation, nucleophilic attack, and can also activate side-chain substituents, e.g. to deprotonation. For examples of reactions, see: Encyclopedia of Reagents for Organic Synthesis, L. A. Paquette, Ed., Wiley, Chichester (1995), vol. 4, p. 2633.

13007-92-6 H66627 Hexacarbonylchromium
六羰基铬

化学属性

Vapor Density	7.6 (vs air)
Vapor Pressure	1 mmHg ( 36 °C)
TSCA	Yes
Boiling Point	220℃
Solubility	不溶
Mol. Formula	C6CrO6
Mol. Weight	220.06
Density	1.77
Appearance	white xtl. white to off-white solid
Melting Point	154-155°C

*以上化合物性质及应用等信息仅供参考

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催化剂

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有机硅

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Hexacarbonylchromium 六羰基铬

规格: 99%

化学属性

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