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(Methoxymethyl)diphenylphosphine oxide ( 甲氧基甲基)二苯基磷氧

规格: 98%
CAS: 4455-77-0
产品编号: H65929
MDL: MFCD00015451
品牌: INFI
Chemical Name(Methoxymethyl)diphenylphosphine oxide
MDL NumberMFCD00015451
CAS Number4455-77-0
Synonym (Methoxymethyl)diphenylphosphine oxide
PubChem Substance ID78203
Beilstein Registry Number649558
EC Number224-704-4
Chemical Name Translation(甲氧甲基)二苯基氧化膦
Reaxys-RN649558
InChIKeyOEPKDBQOTLDTNC-UHFFFAOYSA-N
LabNetwork Molecule IDLN00222937
InChIInChI=1S/C14H15O2P/c1-16-12-17(15,13-8-4-2-5-9-13)14-10-6-3-7-11-14/h2-11H,12H2,1H3
Canonical SMILESCOCP(C1=CC=CC=C1)(C2=CC=CC=C2)=O
  • {ALF} Horner olefination with aldehydes and ketones gives vinyl ethers (and hence higher aldehydes). The method is reported to be superior to the Wittig alternative. The two diastereoisomeric adducts can also be isolated and each converted to a single stereoisomer of the enol ether: J. Chem. Soc., Perkin 1, 3099 (1979):
  • 4455-77-0 H65929 (Methoxymethyl)diphenylphosphine oxide
( 甲氧基甲基)二苯基磷氧

    化学属性

    Mol. FormulaC14H15O2P
    Mol. Weight246.25
    Melting Point113-120 °C
    TSCANo
    Boiling Point334.7±25.0 °C at 760 mmHg
    Density1.0

    *以上化合物性质及应用等信息仅供参考